云南松热解及其热解产物的研究

doi:10.3969/j.issn.1673-5854.2015.04.003

生物质化学工程 ›› 2015, Vol. 49 ›› Issue (4): 14-18.doi: 10.3969/j.issn.1673-5854.2015.04.003

云南松热解及其热解产物的研究

王霏¹, 郑云武^1,2, 郑志锋¹

1. 云南省高校生物质化学炼制与合成重点实验室;西南林业大学材料工程学院, 云南昆明 650224;
2. 东北林业大学材料科学与工程学院, 黑龙江哈尔滨 150040

收稿日期:2015-03-31 出版日期:2015-07-30 发布日期:2015-10-12
通讯作者: 郑志锋(1975—),教授,博士生导师,主要从事生物质能源与材料研究工作;E-mail:zhengzhifeng@swfu.edu.cn。 E-mail:zhengzhifeng@swfu.edu.cn
作者简介:王霏(1990—),男,山东聊城人,硕士生,主要从事生物质热化学转化方面的研究;E-mail:18208809424@163.com
基金资助:
国家林业局引进国际先进林业科学技术项目(2013-4-08);云南省教育厅科学研究基金重大专项项目(ZD2014012)

Yields and Compositions of Products by Pyrolysis of Yunnan Pine

WANG Fei¹, ZHENG Yun-wu^1,2, ZHENG Zhi-feng¹

1. University Key Laboratory of Biomass Chemical Refinery & Synthesis, Yunnan Province; College of Materials Engineering, Southwest Forestry University, Kunming 650224, China;
2. College of Materials Science & Engineering, Northeast Forestry University, Harbin 150040, China

Received:2015-03-31 Online:2015-07-30 Published:2015-10-12

摘要/Abstract

摘要： 采用自制固定床反应器对云南松木粉进行热解,探讨了热解温度、原料颗粒尺寸和氮气流速对云南松热解特性的影响,并采用GC-MS对生物油的组分含量进行分析。结果表明:在热解温度为500 ℃,原料颗粒尺寸为0.250~0.420 mm,氮气流速为150 mL/min条件下,生物油的产率最高为50%,液体组分主要以2,6-二叔丁基对甲酚、2-甲氧基-4-甲基苯酚、异丁香酚、愈创木酚为主,占液体总量的39.24%。

关键词: 云南松, 热解, 热解参数, 生物油, 化学成分

Abstract: The pyrolysis of Yunnan pine was conducted in home-made,fixed-bed reactor.The effects of pyrolysis temperatures,feedstock particle size and nitrogen gas flow rate on characteristic of Yunnan pine pyrolysis were studied.And the compositions of bio-oil were identified by GC-MS.The results showed that:the highest yield of bio-oil was obtained as 50%when the pyrolysis temperature was 500 ℃,particle size was 0.250-0.420 mm,and nitrogen gas flow rate was 150 mL/min.2,6-Di-tert-butyl-p-cresol,2-methoxy-4-methylphenol,isoeugenol,guaiacol composed the main liquid products,and accounted for 39.24%.

Key words: Yunnan pine, pyrolysis, parameters, bio-oil, chemical compositions

中图分类号:

TQ35

王霏, 郑云武, 郑志锋. 云南松热解及其热解产物的研究[J]. 生物质化学工程, 2015, 49(4): 14-18.

WANG Fei, ZHENG Yun-wu, ZHENG Zhi-feng. Yields and Compositions of Products by Pyrolysis of Yunnan Pine[J]. bce, 2015, 49(4): 14-18.

参考文献

[1] GOYAL H B,SEAL D,SAXENA R C.Bio-fuels from thermochemical conversion of renewable resources:A review [J].Renewable & Sustainable Energy Reviews,2008,12(2):504-517.
[2] BASU P.Biomass Gasification and Pyrolysis Practical Design and Theory [M].Beijing:Science Press,2011.
[3] ONAY O.Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis,using a well-swept fixed-bed reactor [J].Fuel Processing Technology,2007,88:523-531.
[4] TENG H,LIN Yu-Chuan,HSU L Y.Production of activated carbons from pyrolysis of waste tires impregnated with potassium hydroxide [J].Journal of the Air & Waste Management Association,2000,50(11):1940-1946.
[5] SHEN Lilly,ZHANG Dong-ke.Low-temperature pyrolysis of sewage sludge and putrescible garbage for fuel oil production [J].Fuel,2005,84(7):809-815.
[6] SEEBAUER V,PETEK J,STAUDINGER G.Effects of particle size,heating rate and pressure on measurement of pyrolysis kinetics by thermogravimetric analysis [J].Fuel,1997,76(13):1277-1282.
[7] COMMANDRÉ J M.Pyrolysis of wood at high temperature:The influence of experimental parameters on gaseous products [J].Fuel Processing Technology,2011,92(5):837-844.
[8] YU Yan-qing,LI Xiang-yu,SU Lu,et al.The role of shape selectivity in catalytic fast pyrolysis of lignin with zeolite catalysts [J].Applied Catalysis A:General,2012,447-448:115-123.
[9] XIAO Rui-rui,YANG Wei.Influence of temperature on organic structure of biomass pyrolysis products [J].Renewable Energy,2013,50:136-141.
[10] STEFANIDIS S D,KALOGIANNIS K G,ILIOPOULOU E F,et al.A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose,hemicellulose and lignin [J].Journal of Analytical and Applied Pyrolysis,2014,105:143-150.
[11] YANG Hai-ping,YAN Rong,CHEN Han-ping,et al.Characteristics of hemicellulose,cellulose and lignin pyrolysis [J].Fuel,2007,86(12/13):1782-1788.
[12] 樊永胜,蔡忆昔,李小花,等.真空热解工艺参数对生物油产率的影响研究[J].林产化学与工业,2014,34(1):79-85.
[13] SEN瘙塁OZ S,ANGIN D.Pyrolysis of safflower (Charthamus tinctorius L.) seed press cake:Part 1.The effects of pyrolysis parameters on the product yields [J].Bioresource Technology,2008,99(13):5492-5497.
[14] ÖZBAY N,PVTVN A E,PVTVN E.Bio-oil production from rapid pyrolysis of cottonseed cake:Product yields and compositions [J].International Journal of Energy Research,2006,30(7):501-510.
[15] ÖZBAY N,UZUN B B,VAROL E A,et al.Comparative analysis of pyrolysis oils and its subfractions under different atmospheric conditions [J].Fuel Processing Technology,2006,87(11):1013-1019.
[16] ÖZBAY N,VAROL E A,UZUN B B,et al.Characterization of bio-oil obtained from fruit pulp pyrolysis [J].Energy,2008,33(8):1233-1240.
[17] UZUN B B,PVTVN A E,PVTVN E.Fast pyrolysis of soybean cake:Product yields and compositions [J].Bioresource Technology,2006,97(4):569-576.
[18] ONAY O,KOÇKAR O M.Fixed-bed pyrolysis of rapeseed (Brassica napus L.)[J].Biomass and Bioenergy,2004,26(3):289-299.
[19] AYSU T,KÜÇÜK M M.Biomass pyrolysis in a fixed-bed reactor:Effects of pyrolysis parameters on product yields and characterization of products [J].Energy,2014,64:1002-1025.
[20] WANG Shu-rong,WANG Kai-ge,LIU Qian,et al.Comparison of the pyrolysis behavior of lignins from different tree species [J].Biotechnology Advances,2009,27(5):562-567.

云南松热解及其热解产物的研究

Yields and Compositions of Products by Pyrolysis of Yunnan Pine

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