生物质化学工程 ›› 2022, Vol. 56 ›› Issue (2): 49-59.doi: 10.3969/j.issn.1673-5854.2022.02.008
收稿日期:
2021-02-05
出版日期:
2022-03-30
发布日期:
2022-03-25
通讯作者:
王景芸
E-mail:977927067@qq.com;wangjingyun0713@163.com
作者简介:
王景芸, 副教授, 博士, 硕士生导师, 从事生物质转化研究; E-mail: wangjingyun0713@163.com基金资助:
Jifeng BAI(), Hongzhu LU, Yu YANG, Manfang CHENG, Jingyun WANG()
Received:
2021-02-05
Online:
2022-03-30
Published:
2022-03-25
Contact:
Jingyun WANG
E-mail:977927067@qq.com;wangjingyun0713@163.com
摘要:
随着绿色合成理念的不断提升, 以具有高催化活性、高稳定性及价格低廉等优势的过渡金属催化剂代替强氧化剂和贵金属催化剂催化氧化5-羟甲基糠醛(HMF)制备精细化学品, 逐渐成为研究者关注的焦点。本文综述了近年来廉价过渡金属基催化剂用于催化HMF氧化制备2, 5-呋喃二甲酸(FDCA)的相关研究, 对该领域的最新研究进行了叙述, 重点介绍了锰基、铜基、铁/钴基、镍基及其他催化体系在HMF氧化反应中的应用, 主要包括锰基金属氧化物、CuCl2催化体系、Fe3O4-CoOx的磁性催化体系等。此外, 在介绍上述催化剂的基础上, 还对廉价过渡金属基催化剂催化HMF氧化制备FDCA的发展前景进行了展望。
中图分类号:
白继峰, 卢虹竹, 杨雨, 程曼芳, 王景芸. 过渡金属催化5-羟甲基糠醛合成2, 5-呋喃二甲酸研究进展[J]. 生物质化学工程, 2022, 56(2): 49-59.
Jifeng BAI, Hongzhu LU, Yu YANG, Manfang CHENG, Jingyun WANG. Research Progress in the Synthesis of 2, 5-Furandicarboxylic Acid from 5-Hydroxymethylfural Catalyzed by Transition Metals[J]. Biomass Chemical Engineering, 2022, 56(2): 49-59.
表1
不同过渡金属催化剂的对比"
催化剂种类 catalyst type | 优点 merit | 缺点 demerit | 活性 activity | 选择性 selectivity | 使用寿命 life | 成本 cost | |
锰基催化剂 Mn-based catalyst | 金属/溴化物 metal/bromide | 反应条件温和 mild reaction conditions | 催化效率低,反应不可控,易污染环境以及难分离low catalytic efficiency, uncontrollable reaction, easy to pollute the environment and difficult to separate | 低 low | 一般 ordinary | 低 low | 低廉 cheap |
金属氧化物 metallic oxide | 易分离,价格低廉 easy to separate, low price | 碱用量高,易产生大量工业废水alkali consumption high, easy to produce a large amount of industrial wastewater | 较高 higher | 较好 good | 大多数可回收 most recyclable | 低廉 cheap | |
铜基催化剂 Cu-based catalyst | CuCl2催化体系CuCl2 catalytic system | 利用其溶解性,使催化剂与反应物达到分子层面的接触,提高了选择性using its solubility, reaching the molecular level contact of the catalyst and the reactants and improving the selectivity | 不易分离,催化剂不易重复使用,且易产生环境污染物not easy to separate, not easy to reuse, and easy to produce environmental pollutants | 一般 ordinary | 较高 higher | 低 low | 低廉 cheap |
负载型催化剂supported catalyst | 载体有孔道结构,高比表面积,催化活性高the carrier has pore structure, high specific surface area and high catalytic activity | 活性组分易流失,活性组分易分布不均the active component is easy to be lost and unevenly distributed | 较高 higher | 一般 ordinary | 低 low | 较高 higher | |
铁、钴基催化剂 Fe/Co-based catalyst | 卟啉配合物催化剂porphyrin complex catalyst | 回收简单方便simple and convenient recycling | 合成步骤繁琐 complex synthesis steps | 较高 higher | 较好 good | 循环使用 6次recycle 6 times | 较高 higher |
氧化物催化剂oxide catalyst | 易分离,合成方式简单easy separation and simple synthesis | 气体为氧化剂,操作不便 gas as oxidant, inconvenient to operate | 较高higher | 较好 good | 大多数可回收 most recyclable | 较低 lower | |
光催化剂 photocatalyst | 反应过程中不会产生污染no contamination occurs during the reaction | 反应条件苛刻 harsh reaction conditions | 较高 higher | 较好 good | 一般不回收 generally not recycled | 较高 higher | |
镍基催化剂 Ni-based catalyst | 可提高贵金属催化剂活性the activity of precious metal catalyst can be improved | 反应时间较长 the reaction time long | 较高 higher | 较好 good | 较低 lower | 较低 lower | |
其他基催化剂 other catalyst | Zr和Fe双金属氧化物催化剂 Zr and Fe bimetallic oxide catalysts | 不使用碱,不会污染环境no use of alkali, no envi-ronmental pollution | 离子液体生产成本较高,合成工工艺复杂the production cost of ionic liquid is high and the synthesis process is complicated | 较高 higher | 较好 good | 一般 ordinary | 较高 higher |
Mo基催化剂 Mo-based catalyst | 溶剂使用水,无毒solvent using water, no toxicity | 反应过程使用碱,易污染环境the reaction process uses alkali, easy to pollute the environment | 较高 higher | 较好 good | 一般 ordinary | 较高 higher |
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