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生物质化学工程 ›› 2021, Vol. 55 ›› Issue (5): 53-59.doi: 10.3969/j.issn.1673-5854.2021.05.009

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衣康酸光固化树脂的研究进展

边均娜1,2, 陈健1, 吴国民1,*(), 孔振武1   

  1. 1. 中国林业科学研究院 林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业和草原局林产化学工程重点实验室; 江苏省生物质能源与材料重点实验室, 江苏 南京 210042
    2. 南京林业大学 江苏省林业资源高效加工利用协同创新中心, 江苏 南京 210037
  • 收稿日期:2020-08-17 出版日期:2021-09-30 发布日期:2021-09-13
  • 通讯作者: 吴国民 E-mail:wooguomin@163.com
  • 作者简介:吴国民, 副研究员, 博士, 硕士生导师, 主要从事天然资源化学与利用研究; E-mail: wooguomin@163.com
    边均娜(1995-), 女, 山东潍坊人, 硕士生, 主要从事生物基水性光固化树脂研究
  • 基金资助:
    中国林科院中央级公益性科研院所基本科研业务费专项资金重点项目(CAFYBB2020GA001)

Progress of Itaconic Acid Light Curable Resins

Junna BIAN1,2, Jian CHEN1, Guomin WU1,*(), Zhenwu KONG1   

  1. 1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China
    2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
  • Received:2020-08-17 Online:2021-09-30 Published:2021-09-13
  • Contact: Guomin WU E-mail:wooguomin@163.com

摘要:

被誉为"绿色技术"的光固化技术,不仅节能环保而且经济高效,已在众多领域得以应用。利用天然可再生资源制备光固化树脂对光固化技术的可持续发展具有重要意义。衣康酸作为一种来源广泛的天然可再生资源,其分子结构中同时含有不饱和双键和两个羧基,可替代丙烯酸、己二酸等石化资源合成各种光固化不饱和树脂,所得树脂综合性能优良。本文综述了衣康酸制备光固化树脂的研究进展,主要包括环氧衣康酸树脂、衣康酸聚酯、衣康酸聚酯丙烯酸酯、衣康酸聚氨酯丙烯酸酯等。由衣康酸合成的光固化树脂在涂料、生物医药和3D打印材料等领域具有重要的应用价值,为生物质资源的高值化利用提供了新途径。

关键词: 生物基, 衣康酸, 光固化树脂, 改性

Abstract:

As a "green technology", the light curing technology which is not only energy-saving, environmental protection but also economical and efficient, has been applied in many fields. The use of natural renewable resources to produce photocurable resins is of great significance to the sustainable development of photocurable technology. As a kind of natural renewable resource, itaconic acid with unsaturated double bond and two carboxyl groups could replace acrylic acid, hexanedioic acid and other petrochemical resources to synthesize various UV light curable unsaturated resins. The synthetic properties of the resin were excellent. The progress of preparation of itaconic acid UV light curable resins was reviewed, including epoxy itaconic acid resin, itaconic acid polyester, itaconic acid polyester acrylate, itaconic acid polyurethane acrylate, etc. The UV light curable resins from itaconic acid would have important application value in the fields of coatings, biomedicine and 3D printing, which could provide a new approach for the high value utilization of biomass products.

Key words: biomass based, itaconic acid, UV light curable resin, modification

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