助剂对镍基生物质焦油重整催化剂性能影响的研究进展

doi:10.3969/j.issn.1673-5854.2019.02.010

生物质化学工程 ›› 2019, Vol. 53 ›› Issue (2): 61-66.doi: 10.3969/j.issn.1673-5854.2019.02.010

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助剂对镍基生物质焦油重整催化剂性能影响的研究进展

王学涛(),苏晓昕

河南科技大学车辆与交通工程学院, 河南洛阳 471003

收稿日期:2018-01-25 出版日期:2019-03-30 发布日期:2019-04-09
作者简介:王学涛(1976—)，男，河南孟津人，教授，博士，硕士生导师，主要从事清洁高效燃烧技术方面的研究; E-mail:wxt7682@163.com
基金资助:
国家自然科学基金资助项目(50806020);河南省自然科学基金资助项目(182300410256)

Research Progress of Influence of Promoters on Performance of Nickel-based Catalyst for Biomass Tar Reforming

Xuetao WANG(),Xiaoxin SU

Henan University of Science and Technology, Vehicle & Transportation Engineering Institute of Hust, Luoyang 471003, China

Received:2018-01-25 Online:2019-03-30 Published:2019-04-09
Supported by:
国家自然科学基金资助项目(50806020);河南省自然科学基金资助项目(182300410256)

摘要/Abstract

摘要：

分别以碱及碱土金属、过渡金属以及稀土金属3种常见助剂类型，探讨了不同助剂对镍基催化剂催化生物质裂解及气化重整制氢催化活性、催化剂物化特性及催化剂失活特性的影响。添加碱金属组分后，生物质热解反应速率会大幅上升，生物质焦的水蒸气气化反应得到促进，并且达到最大热解速率所需的温度也有所降低，热解产物趋向于小分子量产物；过渡金属对生物质气化过程中生成焦油的催化裂解重整具有较好的催化活性；稀土元素对甲醇水蒸气重整等催化反应有着重要的作用，镍基催化剂中加入Ce和Pr能提高甲醇转化率、改善产气组分、提高H₂的选择性。结合国内外的研究情况发现钴、镧等金属助剂有利于提升镍基催化剂重整制氢活性，催化剂积炭及表面活性颗粒的聚集是造成催化剂失活的主要原因。

关键词: 焦油裂解, 水蒸气重整, 镍基催化剂, 助剂

Abstract:

This review discussed the influence of promoters in terms of catalyst performance, physical and chemical properties as well as deactivation characteristics of catalyst from the perspective of alkali and alkaline earth metals, transition metal and rare earth metal, respectively.After the addition of alkali metal components, the biomass pyrolysis reaction rate will increase significantly, the steam gasification reaction of biomass coke will be promoted, and the temperature required to achieve the maximum pyrolysis rate will also decrease, the pyrolysis products tend to be small molecular weight products. The transition metal has good catalytic activity to the catalytic cracking reforming of tar in the gasification process. Rare earth elements play an important role in catalytic reactions such as methanol steam reforming. The addition of Ce and Pr in nickel-based catalysts can improve methanol conversion, gas-producing components and H₂ selectivity. Combined with the domestic and foreign research, it is found that Co, La and other metal promoters are conducive to improving the hydrogen production activity of nickel-based catalyst, while carbon deposition and active particles aggregation are the main causes of catalyst deactivation.

Key words: tar cracking, steam reforming, Ni-based catalyst, promoters

中图分类号:

TQ35
TQ524

王学涛,苏晓昕. 助剂对镍基生物质焦油重整催化剂性能影响的研究进展[J]. 生物质化学工程, 2019, 53(2): 61-66.

Xuetao WANG,Xiaoxin SU. Research Progress of Influence of Promoters on Performance of Nickel-based Catalyst for Biomass Tar Reforming[J]. Biomass Chemical Engineering, 2019, 53(2): 61-66.

图/表 1

参考文献 32

1	谢玉荣, 沈来宏, 肖军, 等. 生物质焦油模拟物重整制取富氢气体实验研究[J]. 燃料化学学报, 2011, 39 (11): 823- 830. doi: 10.3969/j.issn.0253-2409.2011.11.005
2	宋磊, 陈天虎, 陈冬, 等. 凹凸棒石催化重整生物质焦油中的二甲苯[J]. 硅酸盐学报, 2011, 39 (7): 1135- 1139.
3	何立模, 胡松, 汪一, 等. 改性镍基催化剂催化甲苯重整与积碳特性研究[J]. 工程热物理学报, 2016, 37 (5): 1093- 1099.
4	王笑, 高宁博. 生物质气化重整技术的研究进展[J]. 生物质化学工程, 2017, 51 (2): 48- 56.
5	EOM I Y , KIM J Y , KIM T S , et al. Effect of essential inorganic metals on primary thermal degradation of lignocellulosic biomass[J]. Bioresource Technology, 2012, 104 (104): 687- 694.
6	曾志伟, 邹俊, 李斌, 等. 碱金属钾对麦秆水蒸气气化制取富氢气体影响[J]. 中国电机工程学报, 2017, 37 (5): 1434- 1441.
7	JIANG L , HU S , XIANG J , et al. Release characteristics of alkali and alkaline earth metallic species during biomass pyrolysis and steam gasification process[J]. Bioresource Technology, 2012, 116 (71): 278- 284.
8	DU S L , YANG H P , QIAN K Z , et al. Fusion and transformation properties of the inorganic components in biomass ash[J]. Fuel, 2014, 117 (1): 1281- 1287.
9	ZOU J , YANG H P , ZENG Z W , et al. Hydrogen production from pyrolysis catalytic reforming of cellulose in the presence of K alkali metal[J]. International Journal of Hydrogen Energy, 2016, 41 (25): 10598- 10607. doi: 10.1016/j.ijhydene.2016.04.207
10	LI J , ZHANG Q J , ZHAO Y H , et al. Alkaline earth metal oxide modification of Ni/Al₂O₃, for hydrogen production from the partial oxidation and reforming of dimethyl ether[J]. Reaction Kinetics Mechanisms&Catalysis, 2017, 122 (2): 1- 10.
11	MESSAOUDI H , THOMAS S , DJAIDJA A , et al. Hydrogen production over partial oxidation of methane using Ni, Mg, Al spinel catalysts:A kinetic approach[J]. Comptes Rendus Chimie, 2017, 20 (7): 738- 746. doi: 10.1016/j.crci.2017.02.002
12	ZHAN Y Q , HAN J , BAO Z H , et al. Biogas reforming of carbon dioxide to syngas production over Ni-Mg-Al catalysts[J]. Molecular Catalysis, 2017, 436, 248- 258. doi: 10.1016/j.mcat.2017.04.032
13	CHEN F Y , WU C F , DONG L S , et al. Characteristics and catalytic properties of Ni/CaAlO_x, catalyst for hydrogen-enriched syngas production from pyrolysis-steam reforming of biomass sawdust[J]. Applied Catalysis B:Environmental, 2016, 183, 168- 175. doi: 10.1016/j.apcatb.2015.10.028
14	于乃超, 汪丛伟, 阴秀丽, 等. 甘油在改性Ni/γ-Al₂O₃催化剂上水蒸气重整制氢的研究[J]. 现代化工, 2013, 33 (8): 78- 82. doi: 10.3969/j.issn.0253-4320.2013.08.020
15	NI M , LEUNG D Y C , LEUNG M K H . A review on reforming bio-ethanol for hydrogen production[J]. International Journal of Hydrogen Energy, 2007, 32 (15): 3238- 3247. doi: 10.1016/j.ijhydene.2007.04.038
16	邱爱玲, 邵丽丽. Sn修饰的Ni/γ-Al₂O₃催化乙二醇液相重整制氢[J]. 石油化工, 2013, 42 (7): 724- 729. doi: 10.3969/j.issn.1000-8144.2013.07.003
17	杨泽, 李挺, 王美君, 等. Ni基生物质焦油重整催化剂的研究进展[J]. 化工进展, 2016, 35 (10): 3155- 3163.
18	WANG L , LI D L , KOIKE M , et al. Catalytic performance and characterization of Ni-Co catalysts for the steam reforming of biomass tar to synthesis gas[J]. Fuel, 2013, 112 (10): 654- 661.
19	TASAKA K , FURUSAWA T , TSUTSUMI A . Steam gasification of cellulose with cobalt catalysts in a fluidized bed reactor[J]. Energy&Fuels, 2007, 21 (2): 590- 595.
20	DONG L , WU C , LING H , et al. Development of Fe-promoted Ni-Al catalyst for hydrogen production from gasification of wood sawdust[J]. Energy&Fuels, 2017, 31 (3): 2118- 2127.
21	YU Z X , CHEN D , RΦNNING M , et al. Large-scale synthesis of carbon nanofibers on Ni-Fe-Al hydrotalcite derived catalysts:Ⅱ:Effect of Ni/Fe composition on CNF synthesis from ethylene and carbon monoxide[J]. Applied Catalysis A:General, 2008, 338 (1/2): 136- 146.
22	RATKOVIC S , VUJICIC D , KISS E , et al. Different degrees of weak metal-support interaction in Fe-(Ni)/Al₂O₃, catalyst governing activity and selectivity in carbon nanotubes′ production using ethylene[J]. Materials Chemistry&Physics, 2011, 129 (1): 398- 405.
23	LEE J H , LEE E G , JOO O S , et al. Stabilization of Ni/Al₂O₃, catalyst by Cu addition for CO₂, reforming of methane[J]. Applied Catalysis A:General, 2004, 269 (1): 1- 6.
24	CHEN L C , LIN S D . The ethanol steam reforming over Cu-Ni/SiO₂, catalysts:Effect of Cu/Ni ratio[J]. Applied Catalysis B:Environmental, 2011, 106 (3/4): 639- 649.
25	黄媛媛, 巢磊, 李工, 等. Cu-ZrO₂-CeO₂/γ-Al₂O₃催化甲醇水蒸气重整制氢反应的性能[J]. 化工进展, 2017, 36 (1): 216- 223.
26	LI D L , KOIKE M , CHEN J H , et al. Preparation of Ni-Cu/Mg/Al catalysts from hydrotalcite-like compounds for hydrogen production by steam reforming of biomass tar[J]. International Journal of Hydrogen Energy, 2014, 39 (21): 10959- 10970. doi: 10.1016/j.ijhydene.2014.05.062
27	韩雪, 王亚飞, 郝红蕊, 等. 稀土金属在生物乙醇制氢及其相关反应中的应用[J]. 中国稀土学报, 2015, 33 (3): 257- 272.
28	李晓峰, 王晶, 张磊, 等. 铈和镨改性Ni/Al₂O₃催化剂对甲醇水蒸气重整制氢的影响[J]. 中国稀土学报, 2016, (4): 403- 410.
29	LIU X J , LIU S Z , XU P Q . Microwave-assisted Ni-La/γ-Al₂O₃, catalyst for benzene hydrogenation[J]. Russian Journal of Physical Chemistry A, 2017, 91 (11): 2098- 2102. doi: 10.1134/S0036024417110334
30	BAHARI M B , PHUC N H H , ALENAZEY F , et al. Catalytic performance of La-Ni/Al₂O₃, catalyst for CO₂ reforming of ethanol[J]. Catalysis Today, 2017, 291, 67- 75. doi: 10.1016/j.cattod.2017.02.019
31	蔡秀兰, 林维明. 掺杂助剂Ce和Zr的Ni/Al₂O₃催化剂的X光电子能谱分析[J]. 分析测试学报, 2013, 32 (2): 253- 256. doi: 10.3969/j.issn.1004-4957.2013.02.020
32	NIE W X , ZOU X J , SHANG X F , et al. CeO₂-assisted Ni nanocatalysts supported on mesoporous γ-Al₂O₃ for the production of synthetic natural gas[J]. Fuel, 2017, 202, 135- 143. doi: 10.1016/j.fuel.2017.04.026

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助剂对镍基生物质焦油重整催化剂性能影响的研究进展

Research Progress of Influence of Promoters on Performance of Nickel-based Catalyst for Biomass Tar Reforming

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