酶解木质素改性三聚氰胺脲醛树脂的制备与应用

doi:10.3969/j.issn.1673-5854.2018.03.006

生物质化学工程 ›› 2018, Vol. 52 ›› Issue (3): 35-39.doi: 10.3969/j.issn.1673-5854.2018.03.006

酶解木质素改性三聚氰胺脲醛树脂的制备与应用

郭腾飞, 高士帅, 王春鹏

中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2017-02-22 出版日期:2018-05-30 发布日期:2018-05-31
通讯作者: 王春鹏,研究员,博士生导师,主要从事林产资源基高分子复合材料的研究;E-mail:wangcpg@163.com。 E-mail:wangcpg@163.com
作者简介:郭腾飞(1989-),男,安徽亳州人,硕士生,研究方向为生物质高分子材料
基金资助:
中国林业科学研究院林产化学工业研究所研究团队建设创新工程项目（LHSXKQA06）

Synthesis and Application of Melamine Urea Formaldehyde Monolithic Resin Modified by Enzymolysis Lignin

GUO Tengfei, GAO Shishuai, WANG Chunpeng

Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SAF;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2017-02-22 Online:2018-05-30 Published:2018-05-31

摘要/Abstract

摘要： 以酶解木质素（EL）、尿素（U）、甲醛（F）和三聚氰胺（M）为原料，采用碱反应工艺制备了酶解木质素改性三聚氰胺脲醛树脂（ELMUF）。分别考查了EL用量对制备的ELMUF树脂的固化时间、固化温度、游离甲醛量及其制备胶合板胶合强度和甲醛释放量等性能的影响，随着EL用量的增加，ELMUF树脂游离甲醛量从0.26%逐渐降低至0.12%，固化时间从96 s逐渐延长至152 s，黏度由86 mPa·s迅速升高至1 140 mPa·s。通过DSC测定不同EL用量的脲醛树脂固化过程，结果表明：随着EL用量的增加脲醛树脂的反应活性逐渐降低，固化温度由120.6℃逐渐升高至132.0℃，对热压工艺要求更加苛刻。

关键词: 脲醛树脂, 酶解木质素, 固化速度, 胶合强度

Abstract: The enzymolysis lignin modified melamine urea formaldehyde resin(ELMUF) was prepared by using the classic alkali-acid-alkali method with enzymolysis lignin(EL), urea(U), formaldehyde(F) and melamine(M) as raw materials. The influences of the amount of EL on the curing time, curing temperature, free formaldehyde content, the strength and formaldehyde release of the plywood obtained from the prepared ELMUF resin were investigated. With the increase of the amount of EL, the free formaldehyde content decreased from 0.26% to 0.12%, the curing time increased from 96 s to 152 s and the viscosity increased from 86 mPa·s to 1 140 mPa·s. The curing process of resins with different amounts of EL was determined by DSC. The results showed that the introduction of EL could reduce the reactivity of the urea-formaldehyde resin. With the increase of the amount of EL, the curing temperature increased from 120.6℃ to 132.0℃, which required the hot pressing process requirements to be more stringent.

Key words: urea-formaldehyde resin, enzymolysis lignin, curing rate, bonding strength

中图分类号:

TQ35

郭腾飞, 高士帅, 王春鹏. 酶解木质素改性三聚氰胺脲醛树脂的制备与应用[J]. 生物质化学工程, 2018, 52(3): 35-39.

GUO Tengfei, GAO Shishuai, WANG Chunpeng. Synthesis and Application of Melamine Urea Formaldehyde Monolithic Resin Modified by Enzymolysis Lignin[J]. bce, 2018, 52(3): 35-39.

参考文献

[1] YOUNESI-KORDKHEILI H,KAZEMI-NAJAFI S,ESHKIKI R B,et al. Improving urea formaldehyde resin properties by glyoxalated soda bagasse lignin[J]. European Journal of Wood and Wood Products,2015,73(1):77-85.
[2] CAO J K,YAN H Y,SHEN S G,et al. Hydrophilic molecularly imprinted melamine-urea-formaldehyde monolithic resin prepared in water for selective recognition of plant growth regulators[J]. Analytica Chimica Acta,2016,943:136-145.
[3] PAIVA N T,FERRA J M,PEREIRA J,et al. Production of water tolerant melamine-urea-formaldehyde resin by incorporation of sodium metabisulphite[J]. International Journal of Adhesion & Adhesives,2016,70:160-166.
[4] SENSOGUT C,OZALP M,YESIL H. The effect of borax pentahydrate addition to urea formaldehyde on the mechanical characteristics and free formaldehyde content of plywood[J]. International Journal of Adhesion & Adhesives,2009,29(5):589-592.
[5] HAN G,UMEMURA K,KAWAI S,et al. Improvement mechanism of bondability in UF-bonded reed and wheat straw boards by silane coupling agent and extraction treatments[J]. Journal of Wood Science,1999,45(4):299-305.
[6] 李琪,李明,樊茂祥,等. 高醚含量三聚氰胺改性脲醛树脂胶接胶合板性能研究[J]. 林业科技,2016,41(5):25-28.
[7] 甘文玲,高振忠. 三聚氰胺改性脲醛树脂胶粘剂研究进展[J]. 中国胶粘剂,2016,25(6):52-56.
[8] SONG Y,WANG Z X,YAN N,et al. Demethylation of wheat straw alkali lignin for application in phenol formaldehyde adhesives[J/OL]. Polymers,2016,8:1-14[2017-01-22].http://doi.org/10.3390/polym8060209.
[9] ZHAO Y,YAN N,FENG M W. Bark extractives-based phenol-formaldehyde resins from beetle-infested lodgepole pine[J]. Journal of Adhesion Science and Technology,2013,27(18/19):2112-2126.
[10] WANG Z,XUE J W,QU J B,et al. Synthesis of wood lignin-urea-formaldehyde resin adhesive[J]. Advanced Materials Research,2012,560/561:242-246.
[11] 赵晶,陈明,张靖方,等. 酶法糖化玉米芯发酵生产乙醇的研究[J]. 林产化学与工业,2007,27(4):7-10.
[12] 刘志华. 汽爆秸秆高固酶解发酵过程强化的研究[D]. 北京:中国科学院大学博士学位论文,2016.
[13] 王白鸥,孟庆风,崔春红. 生物酶解技术在清汁型大姜浓缩汁生产中的应用[J]. 饮料工业,2003(4):35-38.
[14] LAURICHESSE S,AVÉROUS L. Chemical modification of lignins:Towards biobased polymers[J]. Progress in Polymer Science,2014,39(7):1266-1290.
[15] YOUNESI-KORDKHEILI H,PIZZI A. A Comparison between lignin modified by ionic liquids and glyoxalated lignin as modifiers of urea-formaldehyde resin[J/OL]. The Journal of Adhesion,2016:1-20[2017-01-22]. http://dx.doi.org/10.1080/00218464.2016.1209741.
[16] YOUNESI-KORDKHEILI H,PIZZI A,HONARBAKHSH-RAOUF A,et al. The effect of modified soda bagasse lignin by ionic liquid on properties of urea-formaldehyde resin as wood adhesive[J/OL]. The Journal of Adhesion,2016:1-26[2017-01-22]. https://doi.org/10.1080/00218464.2016.1188284.
[17] PAN H,SHUPE T F,HSE C. Synthesis and cure kinetics of liquefied wood/phenol/formaldehyde resins[J]. Journal of Applied Polymer Science,2008,108(3):1837-1844.

酶解木质素改性三聚氰胺脲醛树脂的制备与应用

Synthesis and Application of Melamine Urea Formaldehyde Monolithic Resin Modified by Enzymolysis Lignin

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