木质纤维水热液化研究进展

doi:10.3969/j.issn.1673-5854.2023.01.010

生物质化学工程 ›› 2023, Vol. 57 ›› Issue (1): 84-98.doi: 10.3969/j.issn.1673-5854.2023.01.010

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木质纤维水热液化研究进展

程琴(), 午紫阳, 马艳, 叶俊, 谭卫红()

中国林业科学研究院林产化学工业研究所; 江苏省生物质能源与材料重点实验室; 国家林业和草原局林产化学工程重点实验室; 林木生物质低碳高效利用国家工程研究中心; 江苏省林业资源高效加工利用协同创新中心, 江苏南京 210042

收稿日期:2021-12-29 出版日期:2023-01-30 发布日期:2023-02-03
通讯作者: 谭卫红 E-mail:Chqazure@163.com;tanweihong71@163.com
作者简介:谭卫红, 副研究员, 硕士生导师, 研究领域: 生物质能源相关的现代仪器分析技术; E-mail: tanweihong71@163.com
程琴(1997-), 女, 贵州贵阳人, 硕士生, 研究方向为木质纤维生物质水热定向转化; E-mail: Chqazure@163.com
基金资助:
国家重点研发计划资助项目(2018YFB1501500)

Research Progress on Hydrothermal Liquefaction of Lignocellulosic Fiber

Qin CHENG(), Ziyang WU, Yan MA, Jun YE, Weihong TAN()

Institute of Chemical Industry of Forest Products, CAF; Key Lab. of Biomass Energy and Material, Jiangsu Province; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass; Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing 210042, China

Received:2021-12-29 Online:2023-01-30 Published:2023-02-03
Contact: Weihong TAN E-mail:Chqazure@163.com;tanweihong71@163.com

摘要/Abstract

摘要：

水热液化是木质纤维生物质的热转化方法之一, 其因以水作为溶剂被认为是环境友好型技术。本文综述了木质纤维生物质水热液化的研究进展, 对木质纤维生物质的水热液化产物分析策略进行概述。分析了纤维素、半纤维素和木质素等木质纤维生物质组分的水热液化机理以及水热液化产物组成和分布。讨论了反应温度、反应时间、催化剂和助溶剂等对木质纤维水热液化的影响, 重点介绍了生物油、不凝性气体和固体残渣等液化产物的表征手段。最后对未来木质纤维水热液化发展方向提出了建议。

关键词: 木质纤维生物质, 水热液化, 生物油, 液化机理, 分析策略

Abstract:

Hydrothermal liquefaction was one of the thermochemical conversions of lignocellulosic biomass. It was considered as an environmentally friendly technology for using water as a solvent. In this review, research progress in hydrothermal liquefaction of lignocellulosic biomass in recent years was summarized and discussed. Analysis strategies of hydrothermal liquefaction products of lignocellulosic biomass were introduced. The hydrothermal liquefaction mechanism of lignocellulosic biomass, such as cellulose, hemicellulose and lignin, and composition and distribution of hydrothermal liquefaction products were analyzed. The effects of reaction temperature, reaction time, catalyst and co-solvent on hydrothermal liquefaction of lignocellulosic biomass were discussed. The characterization methods of liquefaction products such as biological oil, incoagulable gas and solid residue were introduced emphatically. Finally, suggestions were performed on the future development direction of wood fiber hydrothermal liquefaction.

Key words: lignocellulosic biomass, hydrothermal liquefaction, bio-oil, liquefaction mechanism, analysis strategy

中图分类号:

TQ35
TK35

程琴, 午紫阳, 马艳, 叶俊, 谭卫红. 木质纤维水热液化研究进展[J]. 生物质化学工程, 2023, 57(1): 84-98.

Qin CHENG, Ziyang WU, Yan MA, Jun YE, Weihong TAN. Research Progress on Hydrothermal Liquefaction of Lignocellulosic Fiber[J]. Biomass Chemical Engineering, 2023, 57(1): 84-98.

图/表 4

图1

图2

图3

表1

对水热液化产物常采用的分析方法1)"

液化产物liquefaction product	分析手段 analytical method	目的 objective	文献 references
液相产物 liquid products	GC-MS	组分的定性分析characterization of bio-oil components	[30, 38-39, 57, 62, 65, 67-69, 73, 84-85, 92-95]
	GC-FID	组分的定量分析quantitative analysis of bio-oil components	[65, 93]
	Py-GC-MS	结构表征structural characterization	[74]
	HPLC	糖和酸浓度定量分析quantification of sugar and acid concentrations in liquid phase products	[13, 36, 56, 58, 94-96]
	GPC	分子质量测定molecular weight determination	[58, 65, 74, 92]
	氧弹量热计 oxygen-bomb calorimeter	高热值(HHV)测定 high calorific value(HHV) determination	[66]
	FT-IR	官能团分析functional group analysis	[57, 58, 62, 73-74, 84-85, 97]
	ATR/FTIR-ATR	官能团分析functional group analysis	[97]
	DRIFTS	官能团分析functional group analysis	[39]
	¹³C NMR	结构分析structure analysis	[6, 13]
	¹H NMR	结构分析structure analysis	[57, 84]
	³¹P NMR	结构分析structure analysis	[74]
	EA	碳、氢和氧的元素分析elemental analysis of carbon, hydrogen and oxygen in bio-oil	[67-71, 86-87, 94-96]
	TOC分析仪TOC analyzer	总有机碳分析analysis of total organic carbon in bio-oil	[36, 58, 65, 92]
固体残渣 solid residue	EA	碳、氢和氧元素分析analysis of carbon, hydrogen and oxygen	[34, 39, 58, 71, 73-74, 84-85, 92, 97-98]
	TG	热分析thermal analysis	[57, 58, 62, 74]
	DRIFTS	官能团分析functional group analysis	[39]
	¹³C NMR	结构分析structure analysis	[6, 13]
	¹H NMR	结构分析structure analysis	[57, 84]
	³¹P NMR	结构分析structure analysis	[74]
	SEM/TEM	表面形貌和微观结构分析 surface morphology and microstructure analysis	[85]
	XPS	化学成分分析chemical composition analysis	[85]
	XRD	结晶度分析crystallinity analysis	[73]
	比表面积及孔隙度分析仪 surface area and porosity analyzer	比表面积分析specific surface area analysis	[39, 66]
不凝性气体 gas	GC，Micro-GC，GC-TCD	组分测定determination of gas phase product components	[74, 85]

表1

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木质纤维水热液化研究进展

Research Progress on Hydrothermal Liquefaction of Lignocellulosic Fiber

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