纤维素基超疏水材料的现状分析

doi:10.3969/j.issn.1673-5854.2022.01.009

摘要/Abstract

摘要：

近年来超疏水材料的应用领域越来越广泛，对超疏水材料的机械强度、耐磨性、透光度、重复利用性等性能方面的要求越来越高，原料的绿色环保性要求也日渐提高。生物质原料种类多、储量大，占据着可再生资源的主导地位。纤维素作为生物质原料的下游精细产品，具有绿色环保、储量大、应用灵活的优点。本文简单介绍了纤维素基超疏水材料的发展历程、特点及应用，重点分析了水热法、化学沉积法、原子转移自由基聚合和溶胶-凝胶法(纤维素/SiO₂超疏水材料和纤维素基气凝胶)等超疏水改性方法在制备纤维素基超疏水材料中的应用。最后对纤维素基超疏水材料的未来发展进行了展望。

关键词: 纤维素, 超疏水, 疏水改性

Abstract:

In recent years, the application field of superhydrophobic materials has become more and more extensive, and the requirements on mechanical strength, wear resistance, light transmissibility, reuse and other properties of super hydrophobic materials have become higher and higher, and the requirements on green environmental protection of raw materials have been increasing day by day. Biomass materials have many kinds and large volume, which occupy the do minant position of renewable resources. Cellulose, as the downstream fine products of biomass materials, has entered the field of vision of researchers with its advantages of green environmental protection, large reserves and flexible application. This paper briefly indicates the development history, characteristic, and application of superhydrophobic materials and cellulose, the application of superhydrophobic modification methods such as hydrothermal method, chemical deposition method, atom transfer radical polymerization and sol-gel method (cellulose/SiO₂ super-hydrophobic materials and cellulose aerogel) in the preparation of cellulose based superhydrophobic materials was emphatically analyzed. Finally, the future development of cellulosic superhydrophobic materials was prospected.

Key words: cellulose, superhydrophobic, hydrophobic modification

中图分类号:

TQ35
TQ352.8

李晓望, 李煜东, 王鑫, 周加左, 孙晓晗, 赵禹森, 王成毓. 纤维素基超疏水材料的现状分析[J]. 生物质化学工程, 2022, 56(1): 67-74.

Xiaowang LI, Yudong LI, Xin WANG, Jiazuo ZHOU, Xiaohan SUN, Yusen ZHAO, Chengyu WANG. Current Situation of Cellulose Based Superhydrophobic Materials[J]. Biomass Chemical Engineering, 2022, 56(1): 67-74.

图/表 4

参考文献 55

1	SUN T L , FENG L , GAO X F , et al. Bioinspired surfaces with special wettability[J]. Accounts of Chemical Research, 2005, 38 (8): 644- 652. doi: 10.1021/ar040224c
2	倪书振, 王春俭, 戴红旗. 纤维素基超疏水纸的研究进展[J]. 纤维素科学与技术, 2017, 25 (2): 58- 68.
3	江雷, 冯琳. 仿生智能纳米界面材料[M]. 北京: 化学工业出版社, 2007: 51- 52.
4	CELIA E , DARMANIN T , ELISABETH T , et al. Recent advances in designing superhydrophobic surfaces[J]. Journal of Colloid & Interface Science, 2013, 402, 1- 18.
5	COLLINS M N , NECHIFOR M , TANASǍ F , et al. Valorization of lignin in polymer and composite systems for advanced engineering applications: A review[J]. International Journal of Biological Macromolecules, 2019, 131, 828- 849. doi: 10.1016/j.ijbiomac.2019.03.069
6	巫龙辉, 卢生昌, 林新兴, 等. 纤维素基超疏水材料的研究进展[J]. 林产化学与工业, 2016, 36 (6): 119- 126. doi: 10.3969/j.issn.0253-2417.2016.06.018
7	张磊. PDMS基透明超疏水表面的构筑及性能研究[D]. 西安: 陕西科技大学, 2017.
8	ISOGAI A , SAITO T , FUKUZUMI H . TEMPO-oxidized cellulose nanofibers[J]. Nanoscale, 2011, 3 (1): 71- 85. doi: 10.1039/C0NR00583E
9	DE NOOY A E J , BESEMER A C , VAN BEKKUM H . Highly selective nitroxyl radical-mediated oxidation of primary alcohol groups in water-soluble glucans[J]. Carbohydrate Research, 1995, 269 (1): 89- 98. doi: 10.1016/0008-6215(94)00343-E
10	ISOGAI A . Wood nanocelluloses: Fundamentals and applications as new bio-based nanomaterials[J]. Journal of Wood Science, 2013, 59 (6): 449- 459. doi: 10.1007/s10086-013-1365-z
11	LIU M J, WANG S T, JIANG L. Nature-inspired superwettability systems[J/OL]. Nature Reviews Materials, 2017, 2(7): 17036[2020-08-20]. https://doi.org/10.1038/natrevmats.2017.36.
12	LU Y , SATHASIVAM S , SONG J L , et al. Robust self-cleaning surfaces that function when exposed to either air or oil[J]. Science Magazine, 2015, 347 (6226): 1132- 1135.
13	刘鹏程, 王法军, 张丽君, 等. 氧化锌/硅橡胶复合超疏水表面的制备及其自清洁性能[J]. 化工新型材料, 2016, 44 (8): 47- 49.
14	YOUNG T . An essay on the cohesion of fluids[J]. Philosophical Transactions of the Royal Society of London, 1805, 95, 65- 87. doi: 10.1098/rstl.1805.0005
15	DAS S , KUMAR S , SAMAL S K , et al. A review on superhydrophobic polymer nanocoatings: Recent development and applications[J]. Industrial & Engineering Chemistry Research, 2018, 57 (8): 2727- 2745.
16	WENZEL R N . Resistance of solid surfaces to wetting by water[J]. Industrial & Engineering Chemistry, 1936, 28 (8): 988- 994.
17	CASSIE A B D , BAXTER S . Wettability of porous surfaces[J]. Transactions of the Faraday Society, 1944, 40, 546- 551. doi: 10.1039/tf9444000546
18	江雷. 从自然到仿生的超疏水纳米界面材料[J]. 化工进展, 2003, 22 (12): 1258- 1264. doi: 10.3321/j.issn:1000-6613.2003.12.002
19	郭春芳. 超疏水性材料的研究现状及应用[J]. 材料研究与应用, 2010, 4 (3): 161- 163. doi: 10.3969/j.issn.1673-9981.2010.03.001
20	NADA A M A , EL-KADY M Y , EL-SAYED E S A , et al. Preparation and characterization of microcrystalline cellulose (MCC)[J]. Bioresources, 2009, 4 (4): 1359- 1371.
21	SAMIR M A S A , ALLOIN F , DUFRESNE A . Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field[J]. Biomacromolecules, 2005, 6, 612- 626. doi: 10.1021/bm0493685
22	MATHEW A P, CHAKRABORTY A, OKSMAN K, et al. The structure and mechanical properties of cellulose nanocomposites prepared by twin screw extrusion[C]//ACS Symposium Series. Washington, DC: American Chemical Society, 2006: 114-131.
23	SCHURZ J . A bright future for cellulose[J]. Progress in Polymer Science, 1999, 24, 481- 483. doi: 10.1016/S0079-6700(99)00011-8
24	BENDAOUD A , KEHRBUSCH R , BARANOV A , et al. Nanostructured cellulose-xyloglucan blends via ionic liquid/water processing[J]. Carbohydrate Polymers, 2017, 168, 163- 172. doi: 10.1016/j.carbpol.2017.03.080
25	姚一军, 王鸿儒. 纤维素化学改性的研究进展[J]. 材料导报, 2018, 32 (19): 201- 211.
26	WANG Y T, ZHAO X Y, KE C J, et al. Nanosecond laser fabrication of superhydrophobic Ti6Al4V surfaces assisted with different liquids[J/OL]. Colloid and Interface Science Communications, 2020, 35: 100256[2020-08-20]. https://doi.org/10.1016/j.colcom.2020.100256.
27	TUO Y J , ZHANG H F , RONG W T , et al. Drag reduction of anisotropic superhydrophobic surface prepared by laser etching[J]. Langmuir, 2019, 35 (34): 11016- 11022. doi: 10.1021/acs.langmuir.9b01040
28	DONG L T , ZHANG Z A , DING R , et al. Controllable superhydrophobic surfaces with tunable adhesion fabricated by laser interference lithography[J]. Surface and Coatings Technology, 2019, 372, 434- 441. doi: 10.1016/j.surfcoat.2019.05.039
29	XU W T , YI P Y , GAO J , et al. Large-area stable superhydrophobic poly(dimethylsiloxane) films fabricated by thermal curing via a chemically etched template[J]. American Chemical Society Applied Materials & Interfaces, 2020, 12, 3042- 3050.
30	ZHU Y , HE Y , ZHANG J F , et al. Preparation of large-scale, durable, superhydrophobic PTFE films using rough glass templates[J]. Surface and Interface Analysis, 2017, 49 (13): 1422- 1430. doi: 10.1002/sia.6273
31	WANG S Q, XUE Y P, BAN C L, et al. Fabrication of robust tungsten carbide particles reinforced Co-Ni super-hydrophobic composite coating by electrochemical deposition[J/OL]. Surface and Coatings Technology, 2020, 385: 125390[2020-08-20]. https://doi.org/10.1016/j.surfcoat.2020.125390.
32	YANG Z , LIU X P , TIAN Y L . Fabrication of super-hydrophobic nickel film on copper substrate with improved corrosion inhibition by electrodeposition process[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 560, 205- 212.
33	XUE Y P , WANG S Q , ZHAO G C , et al. Fabrication of Ni-Co coating by electrochemical deposition with high super-hydrophobic properties for corrosion protection[J]. Surface and Coatings Technology, 2019, 363, 352- 361. doi: 10.1016/j.surfcoat.2019.02.056
34	ATTAR M R, KHAJAVIAN E, HOSSEINPOUR S, et al. Fabrication of micro-nano roughened surface with superhydropho- bic character on an alu minum alloy surface by a facile chemical etching process[J/OL]. Bulletin of Materials Science, 2019, 43(1): 31[2020-08-20]. https://doi.org/10.1007/S12034-019-1998-7.
35	WANG L , LIANG J Y , HE L . Superhydrophobic and oleophobic surface from fluoropolymer-SiO₂ hybrid nanocomposites[J]. Journal of Colloid and Interface Science, 2014, 435, 75- 82. doi: 10.1016/j.jcis.2014.08.017
36	WANG P , CHEN M J , HAN H L , et al. Transparent and abrasion-resistant superhydrophobic coating with robust self-cleaning function in either air or oil[J]. Journal of Materials Chemistry A, 2016, 4 (20): 7869- 7874. doi: 10.1039/C6TA01082B
37	LU Y , SONG J L , LIU X , et al. Preparation of superoleophobic and superhydrophobic titanium surfaces via an environmentally friendly electrochemical etching method[J]. ACS Sustainable Chemistry & Engineering, 2013, 1 (1): 102- 109.
38	BARSHILIA H C , JOHN S , MAHAJAN V . Nanometric multi-scale rough, transparent and anti-reflective ZnO superhydrophobic coatings on high temperature solar absorber surfaces[J]. Solar Energy Materials and Solar Cells, 2012, 107, 219- 224. doi: 10.1016/j.solmat.2012.06.031
39	HUANG J Y , LI S H , GE M Z , et al. Robust superhydrophobic TiO₂ @ fabrics for UV shielding, self-cleaning and oil-water separation[J]. Journal of Materials Chemistry A, 2015, 3 (6): 2825- 2832. doi: 10.1039/C4TA05332J
40	YUE X J , LI J X , ZHANG T , et al. In situ one-step fabrication of durable superhydrophobic-superoleophilic cellulose/LDH membrane with hierarchical structure for efficiency oil/water separation[J]. Chemical Engineering Journal, 2017, 328, 117- 123. doi: 10.1016/j.cej.2017.07.026
41	朱兆栋, 郑学梅, 付时雨, 等. 纤维素微纳颗粒的硅烷化改性对制备超疏水材料的影响[J]. 中国造纸, 2018, 37 (12): 14- 20. doi: 10.11980/j.issn.0254-508X.2018.12.003
42	DIZGE N , SHAULSKY E , KARANIKOLA V . Electrospun cellulose nanofibers for superhydrophobic and oleophobic membranes[J]. Journal of Membrane Science, 2019, 590 (117): 271- 274.
43	孙长安. 原子转移自由基聚合法改性苎麻纤维的研究[D]. 西安: 陕西师范大学, 2007.
44	YU P X , WANG X , ZHANG K M , et al. Continuous purification of simulated wastewater based on rice straw composites for oil/water separation and removal of heavy metal ions[J]. Cellulose, 2020, 27, 5223- 5239. doi: 10.1007/s10570-020-03135-4
45	WANG Q , MENG G H , WU J N , et al. Novel robust cellulose-based foam with pH and light dual-response for oil recovery[J]. Frontiers of Materials Science, 2018, 12, 118- 128. doi: 10.1007/s11706-018-0420-5
46	HUANG J D , LYU S Y , CHEN Z L , et al. A facile method for fabricating robust cellulose nanocrystal/SiO₂ superhydrophobic coatings[J]. Journal of Colloid and Interface Science, 2019, 536, 349- 362. doi: 10.1016/j.jcis.2018.10.045
47	户岐飞. 苎麻纤维疏水亲油改性条件优化及环境适应性研究[D]. 天津: 天津理工大学. 2018.
48	OGIHARA H , XIE J , OKAGAKI J , et al. Simple method for preparing superhydrophobic paper: Spray-deposited hydrophobic silica nanoparticle coatings exhibit high water-repellency and transparency[J]. Langmuir, 2012, 28 (10): 4605- 4608. doi: 10.1021/la204492q
49	XU X , DONG F H , YANG X X , et al. Preparation and characterization of cellulose grafted with epoxidized soybean oil aerogels for oil-absorbing materials[J]. Journal of Agricultural and Food Chemistry, 2019, 67 (2): 637- 643. doi: 10.1021/acs.jafc.8b05161
50	CHENG H, LI L J, WANG B J, et al. Multifaceted applications of cellulosic porous materials in environment, energy, and health[J/OL]. Progress in Polymer Science, 2020, 106: 101253[2020-08-20]. https://doi.org/10.1016/j.progpolymsci.2020.101253.
51	刘昕昕, 刘志明. 疏水纤维素/SiO₂复合气凝胶的制备和表征[J]. 生物质化学工程, 2016, 50 (2): 39- 44.
52	张恒, 高洪坤, 王哲, 等. 疏水化改性纳米纤维素的制备及应用研究进展[J]. 生物质化学工程, 2019, 53 (1): 61- 66.
53	MULYADI A , ZHANG Z , DENG Y L . Fluorine-free oil absorbents made from cellulose nanofibril aerogels[J]. ACS Applied Materials & Interfaces, 2016, 8 (4): 2732- 2740.
54	孙琳, 刘华玉, 刘坤, 等. 纳米纤维素的疏水改性及应用研究进展[J]. 生物质化学工程, 2020, 54 (4): 57- 66.
55	GAO R N , XIAO S L , GAN W T , et al. Mussel adhesive-inspired design of superhydrophobic nano-fibrillated cellulose aerogels for oil/water separation[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (7): 9047- 9055.

[1]	仲美娟, 刘杏娥, 尚莉莉, 田根林, 杨淑敏, 马建锋. 植物基活性炭孔隙调控研究进展[J]. 生物质化学工程, 2022, 56(1): 57-66.
[2]	吴迪超, 陈超, 侯兴隆, 孙康. 热解温度对纤维素和木质素成炭结构的影响[J]. 生物质化学工程, 2021, 55(3): 1-9.
[3]	王丽娜, 马晓军. 植物纤维素基碳气凝胶的制备及应用研究进展[J]. 生物质化学工程, 2021, 55(1): 83-90.
[4]	尚玮姣,王璐. 基于专利的纳米纤维素技术现状与分析[J]. 生物质化学工程, 2020, 54(4): 49-56.
[5]	孙琳,刘华玉,刘坤,张筱仪,解洪祥,张蕊,李海明,司传领. 纳米纤维素的疏水改性及应用研究进展[J]. 生物质化学工程, 2020, 54(4): 57-66.
[6]	杨浩,陈琪,赵慧敏,顾浩杰,阎杰,林海琳. 甘蔗渣综纤维素膜的制备和性能研究[J]. 生物质化学工程, 2020, 54(2): 6-14.
[7]	王佳楠,羿颖,边勇军,马媛媛,刘志明. 羟甲基化木质素/纤维素气凝胶粒子的制备、表征及吸附性能[J]. 生物质化学工程, 2020, 54(1): 16-22.
[8]	卢琳娜,卢麒麟. 超声波辅助纤维素酶水解制备纳米纤维素[J]. 生物质化学工程, 2020, 54(1): 55-59.
[9]	郑丁源,岳金权,岳大然,李梦扬,张显权. 橡胶木纤维素纳米纤丝/二氧化锰/碳纳米管柔性电极材料的制备及表征[J]. 生物质化学工程, 2019, 53(6): 1-8.
[10]	张强,季红福,周燕,范煜,葛青,肖竹钱,毛建卫. 离子色谱法测毛竹竹叶单糖和糖醛酸组成[J]. 生物质化学工程, 2019, 53(6): 33-38.
[11]	杨嵘晟,朱俊芳,冯树波. 纤维素/超细氧化锌复合气凝胶的制备及抗菌性能研究[J]. 生物质化学工程, 2019, 53(5): 39-43.
[12]	高子翔,张胜南,易维明. 纤维素典型热解产物生成机理研究进展[J]. 生物质化学工程, 2019, 53(5): 57-66.
[13]	葛鑫,程厚富,黄森涛,陈静雯,付甫秀,陈循军,葛建芳. 聚乙烯醇-微晶纤维素-六方氮化硼复合膜制备及性能[J]. 生物质化学工程, 2019, 53(3): 8-14.
[14]	樊洪玉,卫民,赵剑,蒋剑春. 玉米芯木聚糖的提取及其相对分子质量分布研究[J]. 生物质化学工程, 2019, 53(3): 24-32.
[15]	王巍,王云婷,李新宁. 热处理对木质纤维素I_β结构及其力学性能影响的分子动力学模拟[J]. 生物质化学工程, 2019, 53(3): 33-38.