生物质化学工程 ›› 2021, Vol. 55 ›› Issue (4): 66-76.doi: 10.3969/j.issn.1673-5854.2021.04.009
收稿日期:
2020-10-16
出版日期:
2021-07-30
发布日期:
2021-07-10
通讯作者:
周华从
E-mail:hczhou@imut.edu.cn
作者简介:
周华从, 教授, 硕士生导师, 研究领域为低阶碳质资源(生物质、褐煤)高值功能化利用; E-mail: hczhou@imut.edu.cn基金资助:
Xiaolu WANG, Xuefeng YAO, Yuxin CHEN, Huacong ZHOU(), Quansheng LIU
Received:
2020-10-16
Online:
2021-07-30
Published:
2021-07-10
Contact:
Huacong ZHOU
E-mail:hczhou@imut.edu.cn
摘要:
催化转化是可再生生物质资源利用的重要途径,高效催化剂的构建是生物质及其衍生物催化转化的关键环节。生物质衍生羰基类化合物加氢转化为醇或酯类化合物是生物质催化转化利用过程中重要的反应步骤。由于氢转移加氢反应过程具有反应条件温和的优点,因此非均相氢转移加氢催化剂在羰基类生物质平台分子转化中得到广泛应用。过渡金属锆、铪是常用的氢转移加氢反应活性金属。围绕不同锆/铪基氢转移催化剂的制备及其在生物质平台分子加氢转化反应中的应用进行综述。简要介绍了锆、铪氢转移催化剂的制备方法,详细介绍锆氧化物或氢氧化物、不同配体(羟基、羧酸、膦酸、磺酸、钨酸、胺类、有机金属骨架、沸石分子筛)配位锆/铪基催化剂、双金属催化剂,并对比分析它们的催化性能、循环稳定性和结构机理,最后对生物质氢转移加氢催化转化及其催化剂构建发展趋势进行了展望。
中图分类号:
王晓璐, 姚雪峰, 陈宇新, 周华从, 刘全生. 锆/铪基催化剂催化转移加氢反应的研究进展[J]. 生物质化学工程, 2021, 55(4): 66-76.
Xiaolu WANG, Xuefeng YAO, Yuxin CHEN, Huacong ZHOU, Quansheng LIU. Research Progress on Zirconium/Hafnium Based Hydrogen Transfer Catalyst[J]. Biomass Chemical Engineering, 2021, 55(4): 66-76.
表1
氧化锆或氢氧化锆催化剂用于催化加氢反应"
催化剂种类 catalyst | 氢源 hydrogen donor | 温度/℃ temperature | 时间/h time | 反应物 substrate | 转化率/% conversion | 产物 product | 产率/% yield | 参考文献 reference |
ZrO2 | 2-丁醇2-butanol | 150 | 16 | 乙酰丙酸酯 levulinate | 99.9 | γ-戊内酯 γ-valerolactone | 84.7 | [ |
ZrO2 | 乙醇 ethanol | 250 | 3 | 乙酰丙酸乙酯 ethyl levulinate | 95.5 | γ-戊内酯 γ-valerolactone | 81.5 | [ |
ZrO(OH)2·xH2O | 异丙醇 2-isopropanol | 200 | 1 | 乙酰丙酸乙酯 ethyl levulinate | 93.6 | γ-戊内酯 γ-valerolactone | 88.5 | [ |
ZrO(OH)2 | 乙醇 ethanol | 150 | 2.5 | 5 -羟甲基糠醛 5-hydroxymethyl furfural | 94.1 | 2, 5-羟甲基呋喃 2, 5-hydroxymethylfuran | 83.6 | [ |
ZrO2 | 异丙醇 2-isopropanol | 250 | 2 | 肉桂醛 cinnamic aldehyde | 75.0 | 肉桂醇 cinnamyl alcohol | 72.0 | [ |
ZrOCl2·8H2O | 2 -丁醇 2-butanol | 240 | 2 | 乙酰丙酸 levulinic acid | 99.9 | γ-戊内酯 γ-valerolactone | 92.4 | [ |
表2
羟基配位锆/铪基催化剂用于乙酰丙酸乙酯加氢制备γ-戊内酯反应"
催化剂种类1) catalyst | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产率/% yield | NH3-TPD/(mmol·g-1) | CO2-TPD/(mmol·g-1) | 参考文献 reference |
Zr-CA | 130 | 10 | 99.8 | 97.1 | 1.034 | 2.375 | [ |
MZCCP | 160 | 6 | 96.9 | 95.1 | 1.394 | 2.105 | [ |
Zr-TA | 150 | 14 | 93.0 | 96.0 | 0.114 | 0.332 | [ |
Hf-TA | 160 | 46 | 92.2 | 84.4 | 2.077 | 1.1957 | [ |
表3
羧酸配位锆/铪基催化剂用于催化加氢反应1)"
催化剂catalyst | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产率/% yield | TOF值 TOF value | 参考文献 reference | |
金属元素 metal | 配体 ligand | ||||||
Zr | | 70 | 9 | 98.0a | 80.0 a | — | [ |
Zr | | 90 | 6 | 93.4a | 80.9 a | 0.82 | [ |
Zr | | 140 | 4 | 98.0a | 96.0 a | 3.5 | [ |
Zr | 120 | 4 | 95.9a | 92.2 a | — | [ | |
Hf | 120 | 1 | 100.0a | 99.0 a | 0.55 | [ | |
Zr | 150 | 11 | 99.5a | 84.2 a | 0.1 | [ | |
Zr | 150 | 9 | 92.7 b | 90.1 b | 0.09 | [ | |
Hf | 160 | 4 | >99.0 b | 98.0b | 1.53 | [ | |
Hf | 150 | 5 | 95.5 b | 87.7b | 3.51 | [ |
表4
有机膦酸配位锆/铪基催化剂用于催化加氢反应1)"
催化剂catalyst | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产率/% yield | SBET/(m2·g-1) | Vpore/(cm3·g-1) | Dmean/nm | 参考文献 reference | |
金属元素matal | 配体 ligand | ||||||||
Zr | 150 | 6 | 100.0a | 96.7 a | 215 | 0.42 | 8.5 | [ | |
Hf | 150 | 7 | >99.0 a | 97.0 a | 222.6 | 0.25 | 16.7 | [ | |
Zr | 160 | 8 | 100.0 a | 96.2 a | 361 | 0.28 | 3.7 | [ | |
Hf | 160 | 6 | 100.0 a | 85.0 a | 215 | 0.16 | 3.4 | [ | |
Hf | 140 | 4 | 97.6 a | 96.2 a | 241 | 0.52 | 10.0 | [ | |
Zr | 160 | 10 | 93.0 a | 92.0 a | 154 | 0.46 | 12.4 | [ | |
Zr | 180 | 8 | 99.0 a | 95.0 a | 267 | 0.48 | 8.2 | [ | |
Zr | 210 | 2 | 98.1 b | 95.7 b | 248 | — | — | [ | |
Hf | 120 | 2 | 99.2 c | 97.6 c | 214 | 0.21 | 3.4 | [ | |
Zr | 150 | 1.5 | 98.0 c | 96.5 c | 168 | 0.30 | 12.4 | [ |
表6
Zr基双金属催化剂用于催化加氢反应"
催化剂种类 catalyst | 氢源 hydrogen donor | 温度/℃ temperature | 时间/h time | 反应物 substrate | 转化率/% conversion | 产物 product | 产率/% yield | 参考文献 reference |
Al-Zr | 异丙醇2-isopropanol | 220 | 4 | 乙酰丙酸乙酯 ethyl levulinate | 95.5 | γ-戊内酯 γ-valerolactone | 83.2 | [ |
Zr/Fe | 异丙醇 2-isopropanol | 180 | 2 | 糠醛 furfural | 100 | 糠醇 furfuryl alcohol | 99.1 | [ |
Ni/ZrO2 | 异丙醇 2-isopropanol | 120 | 20 | 乙酰丙酸 levulinic acid | — | γ-戊内酯 γ-valerolactone | 88.0 | [ |
Ti/Zr | 异丙醇 2-isopropanol | 180 | 6 | 乙酰丙酸乙酯 ethyl levulinate | 100 | γ-戊内酯 γ-valerolactone | 90.1 | [ |
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