生物质化学工程 ›› 2020, Vol. 54 ›› Issue (6): 83-90.doi: 10.3969/j.issn.1673-5854.2020.06.013
陈权1,2, 夏洪应1,2,*(), 张威2, 张利波1,2
收稿日期:
2019-10-30
出版日期:
2020-11-30
发布日期:
2020-12-01
通讯作者:
夏洪应
E-mail:hyxia@kust.edu.cn
作者简介:
夏洪应,教授,博士生导师,研究领域为微波催化热解生物质; E-mail:hyxia@kust.edu.cn基金资助:
Quan CHEN1,2, Hongying XIA1,2,*(), Wei ZHANG2, Libo ZHANG1,2
Received:
2019-10-30
Online:
2020-11-30
Published:
2020-12-01
Contact:
Hongying XIA
E-mail:hyxia@kust.edu.cn
摘要:
生物质作为可再生资源具有低成本、分布广泛且易得等优点,生物质能的开发利用可有效缓解能源压力,减少环境污染。微波热解技术是生产燃料油和高附加值化学品的有效方法之一,与传统的热解相比,微波热解具有加热速率快、均匀性好、选择性加热、节能与易于控制等优点。在简单分析微波热解产物分布的基础上,详细综述了近年来微波热解生物油产率的影响因素,主要包括热解温度、功率、吸波剂、催化剂、原料预处理、加热时间、原料性质和物料尺寸等因素;最后,总结和展望了微波技术在生物质催化热解制备生物油领域应用中存在的问题、解决途径和发展前景。
中图分类号:
陈权, 夏洪应, 张威, 张利波. 生物质微波热解产生物油的影响因素研究进展[J]. 生物质化学工程, 2020, 54(6): 83-90.
Quan CHEN, Hongying XIA, Wei ZHANG, Libo ZHANG. Research Progress on Influence Factors of Biomass Microwave Pyrolysis for Bio-oil[J]. Biomass Chemical Engineering, 2020, 54(6): 83-90.
表1
不同类型生物质和吸波剂的介电损耗角正切值(2.45 GHz)"
类别types | 物质名称material name | tanδ | 参考文献reference |
生物质 biomass | 白杨树皮aspen bark | 0.22 | [ |
松木pine | 0.19 | [ | |
油棕榈纤维oil palm fiber | 0.08 | [ | |
纤维素cellulose | 0.035 | [ | |
半纤维素hemicelluloses | 0.062 | [ | |
木质素lignin | 0.052 | [ | |
吸波剂 wave absorber | 炭黑carbon black (20 μm) | 0.23 | [ |
石墨碳粉graphite carbon powder(180~250 μm) | 0.4~1.0 | [ | |
石墨粉graphite powder(20~80 μm) | 0.36~0.67 | [ | |
碳化硅SiC | 0.37 | [ | |
活性炭activated carbon | 0.62 | [ | |
生物炭pyrolyzed carbons | 0.20 | [ |
1 |
ELANGOVAN S , TOPF C , FISCHER S , et al. Selective catalytic hydrogenations of nitriles, ketones, and aldehydes by well-defined manganese pincer complexes[J]. Journal of the American Chemical Society, 2016, 138 (28): 8809- 8814.
doi: 10.1021/jacs.6b03709 |
2 |
SALEMA A A , ANI F N . Microwave induced pyrolysis of oil palm biomass[J]. Bioresource Technology, 2011, 102 (3): 3388- 3395.
doi: 10.1016/j.biortech.2010.09.115 |
3 |
BRIDGWATER T . Challenges and opportunities in fast pyrolysis of biomass:Part Ⅰ[J]. Johnson Matthey Technology Review, 2018, 62 (1): 118- 130.
doi: 10.1595/205651318X696693 |
4 | CZERNIK S , BRIDGWATER A V . Overview of applications of biomass fast pyrolysis oil[J]. Energy & Fuels, 2004, 18 (2): 590- 598. |
5 | MOHAN D , PITTMAN JR C U , STEELE P H . Pyrolysis of wood/biomass for bio-oil:A critical review[J]. Energy & Fuels, 2006, 20 (3): 848- 889. |
6 |
ZHANG H D , GAO Z P , AO W Y , et al. Microwave-assisted pyrolysis of textile dyeing sludge using different additives[J]. Journal of Analytical and Applied Pyrolysis, 2017, 127, 140- 149.
doi: 10.1016/j.jaap.2017.08.014 |
7 |
PAYAKKAWAN P , AREEJIT S , SOORAKSA P . Design, fabrication and operation of continuous microwave biomass carbonization system[J]. Renewable Energy, 2014, 66, 49- 55.
doi: 10.1016/j.renene.2013.10.042 |
8 |
BENEROSO D , MONTI T , KOSTAS E T , et al. Microwave pyrolysis of biomass for bio-oil production:Scalable processing concepts[J]. Chemical Engineering Journal, 2017, 316, 481- 498.
doi: 10.1016/j.cej.2017.01.130 |
9 |
ABAS F Z , ANI F N , ZAKARIA Z A . Microwave-assisted production of optimized pyrolysis liquid oil from oil palm fiber[J]. Journal of Cleaner Production, 2018, 182, 404- 413.
doi: 10.1016/j.jclepro.2018.02.052 |
10 | ZHOU R , LEI H W , JULSON J L . Effects of reaction temperature, time and particle size on switchgrass microwave pyrolysis and reaction kinetics[J]. International Journal of Agricultural and Biological Engineering, 2013, 6 (1): 53- 61. |
11 |
MOHAMED B A , KIM C S , ELLIS N , et al. Microwave-assisted catalytic pyrolysis of switchgrass for improving bio-oil and biochar properties[J]. Bioresource Technology, 2016, 201, 121- 132.
doi: 10.1016/j.biortech.2015.10.096 |
12 | CHENG S L , ZHANG Z M , ZHANG D M , et al. Microwave irradiation pyrolysis of rice straw in ionic liquid([Emim]Br)[J]. BioResources, 2013, 8 (3): 3994- 4003. |
13 |
ZHOU R , LEI H W , JULSON J . The effects of pyrolytic conditions on microwave pyrolysis of prairie cordgrass and kinetics[J]. Journal of Analytical and Applied Pyrolysis, 2013, 101, 172- 176.
doi: 10.1016/j.jaap.2013.01.013 |
14 |
HUANG Y F , SHIH C H , CHIUEH P T , et al. Microwave co-pyrolysis of sewage sludge and rice straw[J]. Energy, 2015, 87, 638- 644.
doi: 10.1016/j.energy.2015.05.039 |
15 |
XIE Q L , PENG P , LIU S Y , et al. Fast microwave-assisted catalytic pyrolysis of sewage sludge for bio-oil production[J]. Bioresource Technology, 2014, 172, 162- 168.
doi: 10.1016/j.biortech.2014.09.006 |
16 |
BU Q , LEI H W , WANG L , et al. Biofuel production from catalytic microwave pyrolysis of Douglas fir pellets over ferrum-modified activated carbon catalyst[J]. Journal of Analytical and Applied Pyrolysis, 2015, 112, 74- 79.
doi: 10.1016/j.jaap.2015.02.019 |
17 |
MAŠEK O , BUDARIN V , GRONNOW M , et al. Microwave and slow pyrolysis biochar:Comparison of physical and functional properties[J]. Journal of Analytical and Applied Pyrolysis, 2013, 100, 41- 48.
doi: 10.1016/j.jaap.2012.11.015 |
18 |
BORGES F C , XIE Q L , MIN M , et al. Fast microwave-assisted pyrolysis of microalgae using microwave absorbent and HZSM-5 catalyst[J]. Bioresource Technology, 2014, 166, 518- 526.
doi: 10.1016/j.biortech.2014.05.100 |
19 |
BORGES F C , DU Z Y , XIE Q L , et al. Fast microwave assisted pyrolysis of biomass using microwave absorbent[J]. Bioresource Technology, 2014, 156, 267- 274.
doi: 10.1016/j.biortech.2014.01.038 |
20 |
WU C F , BUDARIN V L , GRONNOW M J , et al. Conventional and microwave-assisted pyrolysis of biomass under different heating rates[J]. Journal of Analytical and Applied Pyrolysis, 2014, 107, 276- 283.
doi: 10.1016/j.jaap.2014.03.012 |
21 |
DOMÍNGUEZ A , MENÉNDEZ J A , INGUANZO M , et al. Production of bio-fuels by high temperature pyrolysis of sewage sludge using conventional and microwave heating[J]. Bioresource Technology, 2006, 97 (10): 1185- 1193.
doi: 10.1016/j.biortech.2005.05.011 |
22 |
FERRERA-LORENZO N , FUENTE E , BERMU'DEZ J M , et al. Conventional and microwave pyrolysis of a macroalgae waste from the Agar-Agar industry.Prospects for bio-fuel production[J]. Bioresource Technology, 2014, 151, 199- 206.
doi: 10.1016/j.biortech.2013.10.047 |
23 |
HUANG Y F , CHIUEH P T , LO S L . A review on microwave pyrolysis of lignocellulosic biomass[J]. Sustainable Environment Research, 2016, 26 (3): 103- 109.
doi: 10.1016/j.serj.2016.04.012 |
24 | MENÉNDEZ J A , DOMÍNGUEZ A , FERNÁNDEZ Y , et al. Evidence of self-gasification during the microwave-induced pyrolysis of coffee hulls[J]. Energy & Fuels, 2007, 21 (1): 373- 378. |
25 |
FRANCO C , PINTO F , GULYURTLU I , et al. The study of reactions influencing the biomass steam gasification process[J]. Fuel, 2003, 82 (7): 835- 842.
doi: 10.1016/S0016-2361(02)00313-7 |
26 | MOEN J , YANG C Y , ZHANG B , et al. Catalytic microwave assisted pyrolysis of aspen[J]. International Journal of Agricultural and Biological Engineering, 2009, 2 (4): 70- 75. |
27 |
MIURA M , KAGA H , SAKURAI A , et al. Rapid pyrolysis of wood block by microwave heating[J]. Journal of Analytical and Applied Pyrolysis, 2004, 71 (1): 187- 199.
doi: 10.1016/S0165-2370(03)00087-1 |
28 |
LAM S S , LIEW R K , WONG Y M , et al. Microwave-assisted pyrolysis with chemical activation, an innovative method to convert orange peel into activated carbon with improved properties as dye adsorbent[J]. Journal of Cleaner Production, 2017, 162, 1376- 1387.
doi: 10.1016/j.jclepro.2017.06.131 |
29 |
KAUDAL B B , APONTE C , BRODIE G . Biochar from biosolids microwaved-pyrolysis:Characteristics and potential for use as growing media amendment[J]. Journal of Analytical and Applied Pyrolysis, 2018, 130, 181- 189.
doi: 10.1016/j.jaap.2018.01.011 |
30 |
AHMAD M , RAJAPAKSHA A U , LIM J E , et al. Biochar as a sorbent for contaminant management in soil and water:A review[J]. Chemosphere, 2014, 99, 19- 33.
doi: 10.1016/j.chemosphere.2013.10.071 |
31 | NAM W L, SU M H, PHANG X Y, et al.Production of bio-fertilizer from microwave vacuum pyrolysis of waste palm shell for cultivation of oyster mushroom(Pleurotus ostreatus)[C]//International Conference on Advances in Energy Systems and Environmental Engineering.[S.l.]: E3S Web of Conferences, 2017, 22: 00122. |
32 |
PARK J H , OK Y S , KIM S H , et al. Competitive adsorption of heavy metals onto sesame straw biochar in aqueous solutions[J]. Chemosphere, 2016, 142, 77- 83.
doi: 10.1016/j.chemosphere.2015.05.093 |
33 |
BRIDGWATER A V , MEIER D , RADLEIN D . An overview of fast pyrolysis of biomass[J]. Organic Geochemistry, 1999, 30 (12): 1479- 1493.
doi: 10.1016/S0146-6380(99)00120-5 |
34 | YU F , DENG S B , CHEN P , et al. Physical and chemical properties of bio-oils from microwave pyrolysis of corn stover[J]. Applied Biochemistry and Biotechnology, 2007, 137, 957- 970. |
35 | DOMÍNGUEZ A , MENÉNDEZ J A , FERNÁNDEZ Y , et al. Conventional and microwave induced pyrolysis of coffee hulls for the production of a hydrogen rich fuel gas[J]. Journal of Analytical & Applied Pyrolysis, 2007, 79 (1/2): 128- 135. |
36 |
HUANG Y F , KUAN W H , LO S L , et al. Total recovery of resources and energy from rice straw using microwave-induced pyrolysis[J]. Bioresource Technology, 2008, 99 (17): 8252- 8258.
doi: 10.1016/j.biortech.2008.03.026 |
37 |
ZHANG B , ZHONG Z P , CHEN P , et al. Microwave-assisted catalytic fast pyrolysis of biomass for bio-oil production using chemical vapor deposition modified HZSM-5 catalyst[J]. Bioresource Technology, 2015, 197, 79- 84.
doi: 10.1016/j.biortech.2015.08.063 |
38 |
FARAG S , FU D B , JESSOP P G , et al. Detailed compositional analysis and structural investigation of a bio-oil from microwave pyrolysis of kraft lignin[J]. Journal of Analytical and Applied Pyrolysis, 2014, 109, 249- 257.
doi: 10.1016/j.jaap.2014.06.005 |
39 |
FERNÁNDEZ Y , MENÉNDEZ J A . Influence of feed characteristics on the microwave-assisted pyrolysis used to produce syngas from biomass wastes[J]. Journal of Analytical and Applied Pyrolysis, 2011, 91 (2): 316- 322.
doi: 10.1016/j.jaap.2011.03.010 |
40 |
ZHANG Y N , CHEN P , LIU S Y , et al. Effects of feedstock characteristics on microwave-assisted pyrolysis:A review[J]. Bioresource Technology, 2017, 230, 143- 151.
doi: 10.1016/j.biortech.2017.01.046 |
41 | SURIAPPARAO D V , PRADEEP N , VINU R . Bio-oil production from Prosopis juliflora via microwave pyrolysis[J]. Energy & Fuels, 2015, 29 (4): 2571- 2581. |
42 |
SHANG H , LU R R , SHANG L , et al. Effect of additives on the microwave-assisted pyrolysis of sawdust[J]. Fuel Processing Technology, 2015, 131, 167- 174.
doi: 10.1016/j.fuproc.2014.11.025 |
43 |
ZHAO X Q , SONG Z L , LIU H Z , et al. Microwave pyrolysis of corn stalk bale:A promising method for direct utilization of large-sized biomass and syngas production[J]. Journal of Analytical and Applied Pyrolysis, 2010, 89 (1): 87- 94.
doi: 10.1016/j.jaap.2010.06.001 |
44 |
ZHANG S P , DONG Q , ZHANG L , et al. Effects of water washing and torrefaction pretreatments on rice husk pyrolysis by microwave heating[J]. Bioresource Technology, 2015, 193, 442- 448.
doi: 10.1016/j.biortech.2015.06.142 |
45 |
HUANG Y F , KUAN W H , CHANG C Y . Effects of particle size, pretreatment, and catalysis on microwave pyrolysis of corn stover[J]. Energy, 2018, 143, 696- 703.
doi: 10.1016/j.energy.2017.11.022 |
46 |
DAGNINO E P , CHAMORRO E R , ROMANO S D , et al. Optimization of the acid pretreatment of rice hulls to obtain fermentable sugars for bioethanol production[J]. Industrial Crops and Products, 2013, 42, 363- 368.
doi: 10.1016/j.indcrop.2012.06.019 |
47 | MUSHTAQ F, CHANNA A S, MAT R, et al.Microwave assisted pyrolysis of waste biomass resources for bio-oil production[C]//Applied Mechanics and Materials.Switzerland: Trans Tech Publications, 2014, 554: 307-311. |
48 |
WAN Y Q , CHEN P , ZHANG B , et al. Microwave-assisted pyrolysis of biomass:Catalysts to improve product selectivity[J]. Journal of Analytical and Applied Pyrolysis, 2009, 86 (1): 161- 167.
doi: 10.1016/j.jaap.2009.05.006 |
49 |
MAMAEVA A , TAHMASEBI A , TIAN L , et al. Microwave-assisted catalytic pyrolysis of lignocellulosic biomass for production of phenolic-rich bio-oil[J]. Bioresource Technology, 2016, 211, 382- 389.
doi: 10.1016/j.biortech.2016.03.120 |
50 |
MOHAMED B A , ELLIS N , KIM C S , et al. Microwave-assisted catalytic biomass pyrolysis:Effects of catalyst mixtures[J]. Applied Catalysis B:Environmental, 2019, 253, 226- 234.
doi: 10.1016/j.apcatb.2019.04.058 |
51 |
CHEN M Q , WANG J , ZHANG M X , et al. Catalytic effects of eight inorganic additives on pyrolysis of pine wood sawdust by microwave heating[J]. Journal of Analytical and Applied Pyrolysis, 2008, 82 (1): 145- 150.
doi: 10.1016/j.jaap.2008.03.001 |
52 | ZHANG X S , RAJAGOPALAN K , LEI H W , et al. An overview of a novel concept in biomass pyrolysis:Microwave irradiation[J]. Sustainable Energy & Fuels, 2017, 1 (8): 1664- 1699. |
53 |
MUSHTAQ F , MAT R , ANI F N . A review on microwave assisted pyrolysis of coal and biomass for fuel production[J]. Renewable and Sustainable Energy Reviews, 2014, 39, 555- 574.
doi: 10.1016/j.rser.2014.07.073 |
54 |
VOS B , MOSMAN J , ZHANG Y , et al. Impregnated carbon as a susceptor material for low loss oxides in dielectric heating[J]. Journal of Materials Science, 2003, 38 (1): 173- 182.
doi: 10.1023/A:1021138505264 |
55 |
SALEMA A A , YEOW Y K , ISHAQUE K , et al. Dielectric properties and microwave heating of oil palm biomass and biochar[J]. Industrial Crops and Products, 2013, 50, 366- 374.
doi: 10.1016/j.indcrop.2013.08.007 |
56 |
NAMAZI A B , ALLEN D G , JIA C Q . Probing microwave heating of lignocellulosic biomasses[J]. Journal of Analytical and Applied Pyrolysis, 2015, 112, 121- 128.
doi: 10.1016/j.jaap.2015.02.009 |
57 | RAMASAMY S , MOGHTADERI B . Dielectric properties of typical Australian wood-based biomass materials at microwave frequency[J]. Energy & Fuels, 2010, 24 (8): 4534- 4548. |
58 | PENG Z W, HWANG J Y, BELL W, et al.Microwave dielectric properties of pyrolyzed carbon[C]//2nd International Symposium on HighTemperature Metallurgical Processing.Hoboken: John Wiley & Sons, Inc., 2011: 77-83. |
59 |
MARTÍN M T , SANZ A B , NOZAL L , et al. Microwave-assisted pyrolysis of Mediterranean forest biomass waste:Bioproduct characterization[J]. Journal of Analytical and Applied Pyrolysis, 2017, 127, 278- 285.
doi: 10.1016/j.jaap.2017.07.024 |
60 | MENÉNDEZ J A , ARENILLAS A , FIDALGO B , et al. Microwave heating processes involving carbon materials[J]. Fuel Processing Technology, 2010, 91 (1): 1- 8. |
61 |
MACQUARRIE D J , CLARK J H , FITZPATRICK E . The microwave pyrolysis of biomass[J]. Biofuels, Bioproducts and Biorefining, 2012, 6 (5): 549- 560.
doi: 10.1002/bbb.1344 |
62 |
LI L J , MA X Q , XU Q , et al. Influence of microwave power, metal oxides and metal salts on the pyrolysis of algae[J]. Bioresource Technology, 2013, 142, 469- 474.
doi: 10.1016/j.biortech.2013.05.080 |
63 | 张新伟, 王鑫, 陈平, 等. 复合微波吸收剂辅助生物质裂解制取生物油研究[J]. 当代化工, 2014, 43 (8): 1407- 1410. |
64 | BU Q.Catalytic microwave pyrolysis of biomass for renewable phenols and fuels[D]. Pullman: Washington State University, 2013. |
65 | CHEN P, XIE Q L, DU Z Y, et al.Microwave-assisted Thermochemical Conversion of Biomass for Biofuel Production[M]//FANG Z, SMITH R L, QI X H.Production of Biofuels and Chemicals with Microwave.Dordrecht: Springer, 2015: 83-98. |
66 |
YIN C G . Microwave-assisted pyrolysis of biomass for liquid biofuels production[J]. Bioresource Technology, 2012, 120, 273- 284.
doi: 10.1016/j.biortech.2012.06.016 |
67 |
SALEMA A A , ANI F N . Pyrolysis of oil palm empty fruit bunch biomass pellets using multimode microwave irradiation[J]. Bioresource Technology, 2012, 125, 102- 107.
doi: 10.1016/j.biortech.2012.08.002 |
68 | 赵延兵, 王鑫, 佟明友. 生物质微波热解影响因素的研究[J]. 当代化工, 2013, 42 (5): 544- 547. |
69 | JANURI Z, RAHMAN N A, IDRIS S S, et al.Effect of activated carbon as microwave absorbance on the yields of microwave assisted pyrolysis of palm oil mill effluent[C]. Kuching: 3rd IET International Conference on Clean Energy and Technology(CEAT), 2014. |
70 |
TIAN Y , ZUO W , REN Z Y , et al. Estimation of a novel method to produce bio-oil from sewage sludge by microwave pyrolysis with the consideration of efficiency and safety[J]. Bioresource Technology, 2011, 102 (2): 2053- 2061.
doi: 10.1016/j.biortech.2010.09.082 |
71 |
HUANG Y F , KUAN W H , CHANG C C , et al. Catalytic and atmospheric effects on microwave pyrolysis of corn stover[J]. Bioresource Technology, 2013, 131, 274- 280.
doi: 10.1016/j.biortech.2012.12.177 |
72 |
BU Q , LEI H W , ZACHER A H , et al. A review of catalytic hydrodeoxygenation of lignin-derived phenols from biomass pyrolysis[J]. Bioresource Technology, 2012, 124, 470- 477.
doi: 10.1016/j.biortech.2012.08.089 |
73 |
LI H , LI J , FAN X L , et al. Insights into the synergetic effect for co-pyrolysis of oil sands and biomass using microwave irradiation[J]. Fuel, 2019, 239, 219- 229.
doi: 10.1016/j.fuel.2018.10.139 |
74 |
MUSHTAQ F , ABDULLAH T A T , MAT R , et al. Optimization and characterization of bio-oil produced by microwave assisted pyrolysis of oil palm shell waste biomass with microwave absorber[J]. Bioresource Technology, 2015, 190, 442- 450.
doi: 10.1016/j.biortech.2015.02.055 |
75 |
MOTASEMI F , AFZAL M T . A review on the microwave-assisted pyrolysis technique[J]. Renewable and Sustainable Energy Reviews, 2013, 28, 317- 330.
doi: 10.1016/j.rser.2013.08.008 |
76 |
WANG X Q , MORRISON W , DU Z Y , et al. Biomass temperature profile development and its implications under the microwave-assisted pyrolysis condition[J]. Applied Energy, 2012, 99, 386- 392.
doi: 10.1016/j.apenergy.2012.05.031 |
77 | WANG L, LEI H W, RUAN R.Techno-economic Analysis of Microwave-assisted Pyrolysis for Production of Biofuels//FANG Z, SMITH JR R L, QI X H.Production of Biofuels and Chemicals with Microwave[M].Dordrecht: Springer, 2015, 251-263. |
78 | ZHAO X , ZHOU H , SIKARWAR V S , et al. Biomass-based chemical looping technologies:The good, the bad and the future[J]. Energy & Environmental Science, 2017, 10 (9): 1885- 1910. |
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