生物质合成气催化甲烷化技术研究进展

doi:10.3969/j.issn.1673-5854.2019.05.009

生物质化学工程 ›› 2019, Vol. 53 ›› Issue (5): 49-56.doi: 10.3969/j.issn.1673-5854.2019.05.009

生物质合成气催化甲烷化技术研究进展

尹航^1,²,徐卫^1,²,孙云娟^1,²,许玉^1,²,应浩^1,^2,*(),宁思云^1,²

1. 中国林业科学研究院林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业和草原局林产化学工程重点实验室; 江苏省生物质能源与材料重点实验室, 江苏南京 210042
2. 南京林业大学江苏省林业资源高效加工利用协同创新中心, 江苏南京 210037

收稿日期:2018-07-09 出版日期:2019-09-30 发布日期:2019-09-27
通讯作者: 应浩 E-mail:hy2478@163.com
作者简介:尹航(1994-),男,黑龙江哈尔滨人,本科,研究方向为生物质热化学转化技术
基金资助:
江苏省林业科技创新与推广项目(LYKJ[2016]47);江苏省生物质能源与材料重点实验室开放基金(JSBEM201801);林业软科学研究项目(2018-R6)

Research Advances in Catalytic Methanation of Bio-syngas

Hang YIN^1,²,Wei XU^1,²,Yunjuan SUN^1,²,Yu XU^1,²,Hao YING^1,^2,*(),Siyun NING^1,²

1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China
2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nangjing 210037, China

Received:2018-07-09 Online:2019-09-30 Published:2019-09-27
Contact: Hao YING E-mail:hy2478@163.com
Supported by:
江苏省林业科技创新与推广项目(LYKJ[2016]47);江苏省生物质能源与材料重点实验室开放基金(JSBEM201801);林业软科学研究项目(2018-R6)

摘要/Abstract

摘要：

天然气因其清洁、高效、使用方便的特点而有着其他化石能源无法比拟的优势。随着天然气需求量的增加，天然气供需矛盾也逐渐凸显，生物质合成气催化制取合成天然气成为解决天然气供需矛盾的技术之一。针对生物质合成气甲烷化过程中存在的问题，从反应过程、催化剂、反应器等方面阐述了生物质合成气甲烷化研究现状；对比了不同催化剂的催化性能，分析得出Ni基催化剂是最适合工业化的甲烷化催化剂之一。列举了国外一些固定床和流化床甲烷化反应器工业化的案例，分析了其各自的生产工艺及优缺点，得出流化床是甲烷化反应器中较为有前景的反应器，并对生物质合成气催化制取合成天然气技术的发展方向进行了展望。

关键词: 合成天然气, 反应器, 催化剂

Abstract:

Natural gas is becoming more and more advantageous than other kinds of fossil energy because it is clean, efficient and convenient to use. With the increasing demand of natural gas, the conflict between supply and demand of natural gas has gradually become increasingly prominent. The catalytic synthesis of synthetic natural gas from biomass synthesis gas has become one of the major technologies to solve the conflict.In allusion to the methanation of biomass synthesis gas, the research status of biomass synthesis gas methanation was explained from the aspects such as reaction process, catalyst and the reactor. Through comparing with the catalytic performance of different catalysts, it was analyzed that Ni-based catalyst was the most suitable for methanation catalyst for industrialization. Some cases of fixed and fluidized bed industrialization from abroad were showed and analyzed their production processes, advantages and disadvantages, it proved that the fluidized bed was very promising in the methanation reactor. Finally, the orientation of developing of biosynthesis gas catalytic synthesis of synthetic natural gas technology was outlooked.

Key words: synthetic natural gas, reactor, catalyst

中图分类号:

TQ35

尹航,徐卫,孙云娟,许玉,应浩,宁思云. 生物质合成气催化甲烷化技术研究进展[J]. 生物质化学工程, 2019, 53(5): 49-56.

Hang YIN,Wei XU,Yunjuan SUN,Yu XU,Hao YING,Siyun NING. Research Advances in Catalytic Methanation of Bio-syngas[J]. Biomass Chemical Engineering, 2019, 53(5): 49-56.

图/表 5

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表2

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图2

图3

参考文献 64

1	蔺华林, 李克健, 赵利军. 煤制天然气高温甲烷化催化剂研究进展[J]. 化工进展, 2011, 30 (8): 1739- 1743.
2	KOPYSCINSKI J , SCHILDHAUER T S , BIOLLAZ S M A . Production of synthetic natural gas (SNG) from coal and dry biomass:A technology review from 1950 to 2009[J]. Fuel, 2010, 89 (8): 1763- 1783. doi: 10.1016/j.fuel.2010.01.027
3	WANG S R , WANG H X , YIN Q Q , et al. Methanation of bio-syngas over a biochar supported catalyst[J]. New Journal of Chemistry, 2010, 89 (8): 1763- 1783.
4	武宏香, 赵增立, 王小波, 等. 生物质气化制备合成天然气技术的研究进展[J]. 化工进展, 2013, 32 (1): 83- 113.
5	DING M Y , TU J L , ZHANG Q , et al. Enhancement of methanation of bio-syngas over CeO₂-modified Ni/Al₂O₃ catalysts[J]. Biomass and Bioenergy, 2016, 85 (5): 12- 17.
6	晏双华, 双建永, 胡四斌. 煤制合成天然气工艺中甲烷化合成技术[J]. 化肥设计, 2010, 48 (2): 19- 22. doi: 10.3969/j.issn.1004-8901.2010.02.004
7	RIBEIRO A M , SANTOS J C , RODRIGUES A E . PSA design for stoichiometric adjustment of bio-syngas for methanol production and co-capture of carbon dioxide[J]. Chemical Engineering Journal, 2010, 163 (3): 355- 363. doi: 10.1016/j.cej.2010.08.015
8	RIBEIRO A M , SANTOS J C , RODRIGUES A E , et al. Syngas stoichiometric adjustment for methanol production and co-capture of carbon dioxide by pressure swing adsorption[J]. Separation Science&Technology, 2012, 47 (6): 850- 866.
9	邢承治, 胡兆吉, 韩启元, 等. 基于催化剂防护及SNG品质的甲烷化工艺设计[J]. 化学工程, 2014, 42 (9): 74- 78. doi: 10.3969/j.issn.1005-9954.2014.09.016
10	董明, 冯飞, 石岭, 等. 生物质合成气催化制取甲烷研究进展[J]. 生物技术进展, 2017, 7 (3): 198- 202.
11	GAO J J , LIU Q , GU F N , et al. Recent advances in methanation catalysts for the production of synthetic natural gas[J]. Rsc Advances, 2015, 5 (29): 22759- 22776. doi: 10.1039/C4RA16114A
12	GAO J J , JIA C M , ZHANG M J , et al. Effect of nickel nanoparticle size in Ni/α-Al₂O₃ on CO methanation reaction for the production of synthetic natural gas[J]. CatalysisScience&Technology, 2013, 3 (8): 2009- 2015.
13	MA S L , TAN Y S , HAN Y Z , et al. Methanation of syngas over coral reef-like Ni/Al₂O₃ catalysts[J]. Journal of Natural Gas Chemistry, 2011, 20 (4): 435- 440. doi: 10.1016/S1003-9953(10)60192-2
14	ZHANG J Y , XIN Z , MENG X , et al. Synthesis, characterization and properties of anti-sintering nickel incorporated MCM-41 methanation catalysts[J]. Fuel, 2013, 109 (7): 693- 701.
15	VARIAVA M F , CHURCH T L , NOORBEHESHT N , et al. Carbon-supported gas-cleaning catalysts enable syn gas methanation at atmospheric pressure[J]. CatalysisScience&Technology, 2014, 5 (1): 515- 524.
16	RYI S K , LEE S W , HWANG K R , et al. Production of synthetic natural gas by means of a catalytic nickel membrane[J]. Fuel, 2012, 94 (1): 64- 69.
17	TAO M , MENG X , XIN Z , et al. Synthesis and characterization of well dispersed nickel-incorporated SBA-15 and its high activity in syngas methanation reaction[J]. Applied Catalysis A:General, 2016, 516, 127- 134. doi: 10.1016/j.apcata.2016.02.019
18	CHENG C B , SHEN D , XIAO R , et al. Methanation of syngas (H₂/CO) over the different Ni-based catalysts[J]. Fuel, 2017, 189, 419- 427. doi: 10.1016/j.fuel.2016.10.122
19	BIAN Z C , MENG X , TAO M , et al. Uniform Ni particles on amino-functionalized SBA-16 with excellent activity and stability for syngas methanation[J]. Journal of Molecular Catalysis A:Chemical, 2016, 147, 184- 191.
20	LIU Z H , CHU B Z , ZHAI X L , et al. Total methanation of syngas to synthetic natural gas over Ni catalyst in a micro-channel reactor[J]. Fuel, 2012, 95 (1): 599- 605.
21	ZHU H W , RAZZAQ R , JIANG L , et al. Low-temperature methanation of CO in coke oven gas using single nanosized Co₃O₄ catalysts[J]. Catalysis Communications, 2012, 23 (21): 43- 47.
22	CHEN X , JIN J H , SHA G Y , et al. Silicon-nickel intermetallic compounds supported on silica as a highly efficient catalyst for CO methanation[J]. Catalysis Science & Technology, 2013, 4 (1): 53- 61.
23	DU G A , LIM S Y , YANG Y H , et al. Methanation of carbon dioxide on Ni-incorporated MCM-41 catalysts:The influence of catalyst pretreatment and study of steady-state reaction[J]. Journal of Catalysis, 2007, 249 (2): 370- 379. doi: 10.1016/j.jcat.2007.03.029
24	TADA S , SHIMIZU T , KAMEYAMA H , et al. Ni/CeO₂ catalysts with high CO₂ methanation activity and high CH₄ selectivity at low temperatures[J]. International Journal of Hydrogen Energy, 2017, 37 (7): 5527- 5531.
25	RAHMANI S , REZAEI M , MESHKANI F . Preparation of highly active nickel catalysts supported on mesoporous nanocrystalline γ-Al₂O₃ for CO₂ methanation[J]. Journal of Industrial and Engineering Chemistry, 2014, 20 (4): 1346- 1352. doi: 10.1016/j.jiec.2013.07.017
26	AZIZ M A A , JALIL A A , TRIWAHYONO S , et al. Highly active Ni-promoted mesostructured silica nanoparticles for CO₂ methanation[J]. Applied Catalysis B:Environmental, 2014, 147 (7): 359- 368.
27	LIU J , LI C M , WANG F , et al. Enhanced low-temperature activity of CO₂ methanation over highly-dispersed Ni/TiO₂ catalyst[J]. Rsc Advances, 2013, 3 (10): 2627- 2633.
28	ALDANA P A U , OCAMPO F , KOBL K , et al. Catalytic CO₂ valorization into CH₄ on Ni-based ceria-zirconia.Reaction mechanism by operando IR spectroscopy[J]. Catalysis Today, 2013, 215 (1): 201- 207.
29	ZHOU G L , WU T , XIE H M , et al. Effects of structure on the carbon dioxide methanation performance of Co-based catalysts[J]. International Journal of Hydrogen Energy, 2013, 38 (24): 10012- 10018. doi: 10.1016/j.ijhydene.2013.05.130
30	ABE T , TANIZAWA M , WATANABE K , et al. CO₂ methanation property of Ru nanoparticle-loaded TiO₂ prepared by a polygonal barrel-sputtering method[J]. Energy&Environmental Science, 2009, 2 (3): 315- 321.
31	GARBARINO G , BELLOTTI D , FINOCCHIO E , et al. Methanation of carbon dioxide on Ru/Al₂O₃:Catalytic activity and infrared study[J]. Catalysis Today, 2016, 277, 21- 28. doi: 10.1016/j.cattod.2015.12.010
32	ABDEL-MAGEED A M , WIDMANN D , OLESEN S E , et al. Selective CO methanation on Ru/TiO₂catalysts:Role and influence ofmetal-support interactions[J]. Acs Catalysis, 2015, 5 (11): 6753- 6763. doi: 10.1021/acscatal.5b01520
33	KWAK J H , KOVARIK L , SZANVI J . CO₂ reduction on supported Ru/Al₂O₃ catalysts:Cluster size dependence of product selectivity[J]. Acs Catalysis, 2013, 3 (11): 2449- 2455. doi: 10.1021/cs400381f
34	GARBARINO G , BELLOTTI D , RIANI P , et al. Methanation of carbon dioxide on Ru/Al₂O₃ and Ni/Al₂O₃ catalysts at atmospheric pressure:Catalysts activation, behaviour and stability[J]. International Journal of Hydrogen Energy, 2015, 40 (30): 9171- 9182. doi: 10.1016/j.ijhydene.2015.05.059
35	路霞, 陈世恒, 王万丽, 等. CO甲烷化Ni基催化剂的研究进展[J]. 石油化工, 2010, 39 (3): 340- 345.
36	胡大成, 高加俭, 贾春苗, 等. 甲烷化催化剂及反应机理的研究进展[J]. 过程工程学报, 2011, 11 (5): 880- 893.
37	CHONGBO C , DEKUI S , RUI X , et al. Methanationof syngas (H₂/CO) over the different Ni-based catalysts[J]. Fuel, 2017, 189, 419- 427. doi: 10.1016/j.fuel.2016.10.122
38	喻磊, 陈卫昌, 邢建东, 等. Ni-Co双金属催化剂应用于CO₂甲烷化的研究[J]. 现代化工, 2016, (9): 126- 130.
39	王昱涵, 白思雨, 崔丽杰, 等. Ni-Mo双金属催化剂的甲烷化性能与耐硫稳定性[J]. 化工学报, 2018, 69 (5): 2063- 2072.
40	TAKENAKA S , SHIMIZU T , OTSUKA K , et al. Complete removal of carbon monoxide in hydrogen-rich gasstream through methanation over supported metal catalysts[J]. International Journal of Hydrogen Energy, 2004, 29 (10): 1065- 1073. doi: 10.1016/j.ijhydene.2003.10.009
41	刘伟. 合成气制天然气甲烷化催化剂的研究进展[J]. 石油化工, 2018, 47 (2): 197- 202. doi: 10.3969/j.issn.1000-8144.2018.02.015
42	LE T A , KIM M S , LEE S H , et al. CO and CO₂ methanation over supported Ni catalysts[J]. Catalysis Today, 2017, 293
43	詹吉山, 郭翠梨, 张俊涛, 等. TiO₂对Ni/Al₂O₃催化剂CO甲烷化性能的影响[J]. 燃料化学学报, 2012, 40 (5): 589- 593. doi: 10.3969/j.issn.0253-2409.2012.05.013
44	刘玉成, 凡美婷, 冯雅晨, 等. La助剂对高温甲烷化催化剂的影响[J]. 天然气化工(C1化学与化工), 2018, 43 (5): 10- 14.
45	王煜炎, 吴刚强, 郎中敏, 等. Ce助剂对负载型Ni/TiO₂催化剂CO甲烷化性能的影响[J]. 现代化工, 2017, (9): 107- 109, 111.
46	崔晓曦, 孟凡会, 何忠, 等. 助剂对Ni基催化剂结构及甲烷化性能的影响[J]. 无机化学学报, 2014, 30 (2): 277- 283.
47	朱警, 戴伟, 穆玮, 等. 选择加氢催化剂载体氧化铝的改性及其工业应用(Ⅰ)[J]. 化工进展, 2004, 23 (2): 192- 194. doi: 10.3321/j.issn:1000-6613.2004.02.015
48	SONG K H , YAN X , CHUNG J S , et al. La effect on the long-term durability of Ni-Mg-Al₂O₃ catalysts for syngas methanation[J]. Applied Catalysis A:General, 2017, 530, 184- 192. doi: 10.1016/j.apcata.2016.11.002
49	曹红霞.CO/CO₂甲烷化催化剂的制备、表征及性能研究[D].徐州:中国矿业大学, 2018.
50	符世龙, 陈应泉, 杨海平. 生物质合成气甲烷化催化剂研究进展[J]. 沈阳农业大学学报, 2017, 48 (4): 488- 496.
51	LI Y K , ZHANG Q F , CHAI R J , et al. Metal-foam-structured Ni-Al₂O₃ catalysts:Wet chemical etching preparation and syngas methanation performance[J]. Applied Catalysis A:General, 2016, 510, 216- 226. doi: 10.1016/j.apcata.2015.11.034
52	CHENG C , SHEN D , XIAO R , et al. Methanation of syngas (H₂/CO) over the different Ni-based catalysts[J]. Fuel, 2017, 189, 419- 427. doi: 10.1016/j.fuel.2016.10.122
53	吴连弟, 陈幸达, 王文明, 等. 两种煤气甲烷化反应器的模拟和比较[J]. 煤炭转化, 2006, 29 (2): 70- 75. doi: 10.3969/j.issn.1004-4248.2006.02.017
54	宋鹏飞, 侯建国, 王秀林, 等. 绝热多段固定床甲烷化反应器设计中几个问题的研究[J]. 现代化工, 2014, 34 (10): 143- 145.
55	TOPSØE H.From solid fuels to substitute natural gas (SNG) using TREMP^TM[EB/OL]. 2009[2018-06-11].http://www.topsoe.com/business_areas/gasification_based.aspx.
56	RASMUSSEN N B.Technologies relevant for gasification and methanation in Denmark[R].Aalborg: Danish Gas Technology Centre Hoersholm, 2012-09-18.
57	李安学, 李春启, 左玉帮, 等. 合成气甲烷化工艺技术研究进展[J]. 化工进展, 2015, 34 (11): 3898- 3905.
58	WOOD C D , GLEASON E F . Catalyst for producing methane from hydrogen and carbon monoxide[J]. Industrial and Engineering Chemistry, 1955, 68- 70.
59	FRIEDRICHS G, PROPLESCH P, WISMANN G, et al.Methanisierung von kohlevergasungsgasen im wirbelbett pilot-entwicklungsstufe schlussbericht[R].[s.l.]: Forschungsbericht Universitat Karlsruhe, 1985: 85-106.
60	AHREJFELDT J , JØRGENSEN B , THOMSEN T . Bio-SNG Potential Assessment:Denmark 2020[M]. Roskilde: Danmarks Tekniske Universitet, 2010.
61	SEEMANN M C , SCHILDHAUER T J , BIOLLAZ S M A . Fluidized bed methanation of wood-derived producer gas for the production of synthetic natural gas[J]. Industrial&Engineering Chemistry Research, 2010, 49 (15): 7034- 7038.
62	COUSINS A , ZHUO Y , GEORGE A , et al. Development of a bench-scale high-pressure fluidized bed reactor and its sequential modification for studying diverse aspects of pyrolysis and gasification of coal and biomass[J]. Energy&Fuels, 2008, 22, 2491- 2503.
63	KOPYSCINSKI J , SCHIDHAUER T J , BIOLLAZ S M A . Methanation in a fluidized bed reactor with high initial CO partial pressure:Part Ⅰ. Experimental investigation of hydrodynamics, mass transfer effects, and carbon deposition[J]. Chemical Engineering Science, 2011, 66 (5): 924- 934. doi: 10.1016/j.ces.2010.11.042
64	KOPYSCINSKI J , SCHILDHAUER T J , BIOLLAZ S M A . Methanation in a fluidized bed reactor with high initial CO partial pressure:Part Ⅱ.Modeling and sensitivity study[J]. Chemical Engineering Science, 2011, 66 (8): 1612- 1621. doi: 10.1016/j.ces.2010.12.029

催化剂 catalyst	制备方法 preparation method	活性组分/% active component	温度/℃ temperature	压力/MPa pressure	CO转化率/% CO conversion	CH₄选择率/% CH₄ selectivity	测试时长/h stability test time	参考文献 reference
Ni- α-Al₂O₃	I	10	450	0.1	96.0	90.0	50	[12]
Ni-Al₂O₃	CP	15	400	0.1	98.2	84.7	120	[13]
Ni/MCM-41	HT	10	350	0.1	97.9	88.2	100	[14]
Ni/MWNTs	I	13	350	0.1	95.0	85.0	240	[15]
Ni-membrane	I	99.9	350	0.2	95.0	96.0	—	[16]
Ni-SBA-15	pH	3.6	350	0.3	100.0	98.6	100	[17]
Ni/CeO₂-Al₂O₃	I	10	350	—	—	80.0	—	[5]
Ni-Fe/Al₂O₃	I	15	262	0.1	95.0	90.0	24	[18]
Ni-SBA-16-NH₂	I	10	350	0.3	100.0	99.9	100	[19]
Ni-AlOOH-Al₂O₃	I	28	550	0.3	98.0	92.0	—	[20]
Co₃O₄	CP	—	300	2.0	100.0	—	—	[21]
Ru/ABC	I	0.3	350	—	97.0	92.0	—	[3]
Si-Ni/SiO₂	SI	20	350	0.1	70.0	60.0	42	[22]

催化剂 catalyst	制备方法¹⁾ preparation method	活性组分/% active component	温度/℃ temperature	压力/MPa pressure	CO₂转化率/% CO₂ conversion	CH₄选择率/% CH₄ selectivity	测试时长/h stability test time	参考文献 reference
Ni/MCM-41	HT	10	400	0.1	56.5	96.0	—	[23]
Ni-CeO₂	I	5	300	0.1	55.0	100.0	—	[24]
Ni/ γ-Al₂O₃	I	3	350	0.1	83.6	100.0	10	[25]
Ni/MSN	I	15	300	0.1	64.1	99.9	200	[26]
Ni-TiO₂	CP	5	218	0.1	96.0	99.0	—	[27]
Ni/CeO₂-ZrO₃	SG	20	350	0.1	79.7	97.3	90	[28]
Co/KIT-6	I	0.8	260	0.1	48.9	100.0	—	[29]
Ru-TiO₂	BS	20	180	0.1	—	100.0	170	[30]
Ru/ γ-Al₂O₃	I	3	350	0.1	85.0	85.0	2	[31]

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生物质合成气催化甲烷化技术研究进展

Research Advances in Catalytic Methanation of Bio-syngas

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