生物质化学工程 ›› 2019, Vol. 53 ›› Issue (3): 1-7.doi: 10.3969/j.issn.1673-5854.2019.03.001
• 研究报告 • 下一篇
陈博1,2,黄元波1,2,王培燕1,2,刘守庆1,2,宁德鲁3,郑志锋1,2,4,*()
收稿日期:
2018-11-05
出版日期:
2019-05-30
发布日期:
2019-06-04
通讯作者:
郑志锋
E-mail:zhifeng.zheng@xmu.edu.cn
作者简介:
陈博(1992—),男,河南驻马店人,硕士生,主要从事介孔材料的制备及其对脂肪酸的分离研究
基金资助:
Bo CHEN1,2,Yuanbo HUANG1,2,Peiyan WANG1,2,Shouqing LIU1,2,Delu NING3,Zhifeng ZHENG1,2,4,*()
Received:
2018-11-05
Online:
2019-05-30
Published:
2019-06-04
Contact:
Zhifeng ZHENG
E-mail:zhifeng.zheng@xmu.edu.cn
Supported by:
摘要:
以介孔分子筛SBA-15作为载体,在3-氨基丙基三乙氧基硅烷(APTS)对SBA-15表面修饰的基础上负载银离子制备Ag+-APTS/SBA-15吸附剂,采用氮气吸附-脱附、X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、透射电镜(TEM)、扫描电镜-能谱(SEM-EDS)对吸附剂进行表征,并将吸附剂应用于混合脂肪酸甲酯的分离以考察其吸附性能。氮气吸附-脱附、XRD和TEM分析结果可以看出,制备的吸附剂具有规则有序孔道结构;FT-IR数据显示,介孔SBA-15表面被APTS成功修饰;SEM-EDS结果表明,银离子成功负载到载体SBA-15上;对混合脂肪酸甲酯吸附研究表明,该吸附剂对不饱和脂肪酸甲酯(UFAMEs)吸附效果较好,且随着银离子负载量的增加以及UFAMEs双键数的增多,吸附效果增强;当银离子负载量为25%时,吸附剂对亚麻酸甲酯吸附率高达53.47%。
中图分类号:
陈博,黄元波,王培燕,刘守庆,宁德鲁,郑志锋. 载银介孔SBA-15吸附剂的制备及其对脂肪酸甲酯的吸附研究[J]. 生物质化学工程, 2019, 53(3): 1-7.
Bo CHEN,Yuanbo HUANG,Peiyan WANG,Shouqing LIU,Delu NING,Zhifeng ZHENG. Preparation of Silver Ion-loaded Mesoporous SBA-15 Adsorbent and Its Application in Adsorption of Fatty Acids Methyl Ester[J]. Biomass Chemical Engineering, 2019, 53(3): 1-7.
表2
吸附剂对脂肪酸甲酯的吸附性能"
吸附剂 adsorbent | 吸附率adsorption rate/% | ||||
棕榈酸甲酯 methyl palmitate | 硬脂酸甲酯 methyl stearate | 油酸甲酯 methyl oleate | 亚油酸甲酯 methyl linoleate | 亚麻酸甲酯 methyl linolenate | |
SBA-15 | 2.38 | 3.65 | 2.67 | 6.67 | 1.33 |
APTS/SBA-15 | 1.57 | 1.20 | 9.10 | 5.45 | 3.64 |
15% Ag+-APTS/SBA-15 | 2.04 | 1.75 | 8.50 | 16.67 | 17.35 |
20% Ag+-APTS/SBA-15 | 2.12 | 2.46 | 10.62 | 17.36 | 30.47 |
25% Ag+-APTS/SBA-15 | 3.61 | 2.44 | 13.47 | 18.78 | 53.47 |
1 | 胡金杰, 曹霞, 吴志锋. ω-3多不饱和脂肪酸在养猪生产中的研究进展[J]. 粮食与饲料工业, 2017, 12 (1): 48- 52. |
2 | 刘志国, 王华林, 王丽梅, 等. 多不饱和脂肪酸对神经细胞保护作用的研究进展[J]. 食品科学, 2016, 37 (7): 239- 248. |
3 |
DESBOIS A P , SMITH V J . Antibacterial free fatty acids: Activities, mechanisms of action and biotechnological potential[J]. Applied Microbiology and Biotechnology, 2010, 85 (6): 1629- 1642.
doi: 10.1007/s00253-009-2355-3 |
4 |
ANSORGE-SCHUMACHER M B , THUM O . Immobilised lipases in the cosmetics industry[J]. Chemical Society Reviews, 2013, 42 (15): 6475- 6490.
doi: 10.1039/c3cs35484a |
5 |
PRAAGMAN J , BEULENS J W , ALSSEMA M , et al. The association between dietary saturated fatty acids and ischemic heart disease depends on the type and source of fatty acid in the European prospective investigation into cancer and nutrition-netherlands cohort[J]. American Journal of Clinical Nutrition, 2016, 103 (2): 356- 365.
doi: 10.3945/ajcn.115.122671 |
6 |
WIJESUNDERA R C , RATNAYAKE W M N , ACKMAN R G . Eicosapentaenoic acid geometrical isomer artifacts in heated fish oil esters[J]. Journal of the American Oil Chemists Society, 1989, 66 (12): 1822- 1830.
doi: 10.1007/BF02660756 |
7 | YANG J , XIE C , XU J , et al. Separation and characterization of polyunsaturated fatty acids from rubber seed oil[J]. Chemistry and Industry of Forest Products, 2013, 33 (2): 49- 54. |
8 | ZHANG Q Y . Separating unsaturated fatty acid from perilla oil with the crystallizing process under low temperature[J]. Journal of Liaoning Institute of Science and Technology, 2014, 16 (1): 8- 10. |
9 |
MCKENNEDY J , ÖNENÇ S , PALA M , et al. Supercritical carbon dioxide treatment of the microalgae Nannochloropsis oculata, for the production of fatty acid methyl esters[J]. Journal of Supercritical Fluids, 2016, 116, 264- 270.
doi: 10.1016/j.supflu.2016.06.003 |
10 | HONG F , YONG Q A . Preparation of polyunsaturated fatty acids from fish oil with molecular distillation[J]. Journal of Wuxi University of Light Industry, 2002, 21 (6): 617- 621. |
11 | 程楠.鱼油脂肪酸乙酯制备及分离纯化研究[D].天津:天津大学, 2014. |
12 | DILLON J T , APONTE J C , TAROZO R , et al. Purification of omega-3 polyunsaturated fatty acids from fish oil using silver-thiolate chromatographic material and high performance liquid chromatography[J]. Journal of Chromatography A, 2013, 1312 (17): 18- 25. |
13 | LI M , PHAM P J , JR PITTMAN C U , et al. SBA-15-supported ionic liquid compounds containing silver salts: Novel mesoporous π-complexing sorbents for separating polyunsaturated fatty acid methyl esters[J]. Microporous and Mesoporous Materials, 2009, 117 (1/2): 436- 443. |
14 | 于俊雅, 张晨曦, 倪芳, 等. 负载Ag+氧化铝陶瓷膜的制备及其对角鲨烯、花生四烯酸和二十碳五烯酸的吸附特性[J]. 生物加工工程, 2017, 15 (1): 8- 15. |
15 | MA H , HUANG Y B , ZHENG Z F , et al. Phosphotungstic acid based mesoporous silica catalysts for the preparation of soybean oil-based polyols[J]. Catalysis Letters, 2017, 147 (3): 1- 11. |
16 |
ZHAO D Y , HUO Q S , FENG J L , et al. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures[J]. Journal of the American Chemical Society, 1998, 120 (24): 6024- 6036.
doi: 10.1021/ja974025i |
17 |
王兴慧, 朱桂茹, 高从堦. 短孔道介孔二氧化硅SBA-15对铀的吸附性能[J]. 化工学报, 2013, 64 (7): 2480- 2487.
doi: 10.3969/j.issn.0438-1157.2013.07.024 |
18 |
WIJESUNDERA R C , RATNAYAKE W M N , ACKMAN R G . Eicosapentaenoic acid geometrical isomer artifacts in heated fish oil esters[J]. Journal of the American Oil Chemists' Society, 1989, 66 (12): 1822- 1830.
doi: 10.1007/BF02660756 |
19 |
LANZAFAME P , PERATHONER S , CENTI G , et al. Synthesis and characterization of Co-containing SBA-15 catalysts[J]. Journal of Porous Materials, 2007, 14 (3): 305- 313.
doi: 10.1007/s10934-006-9068-0 |
20 | ESWARAMOORTHI I , DALAI A K . Synthesis, characterization and catalytic performance of boron substituted SBA-15 molecular sieves[J]. Microporous and Mesoporous Materials, 2006, 93 (1/2/3): 1- 11. |
21 | BELAUNZARAN X , BRAVO-LAAS L , KRAMER J K G , et al. Limitation of using silver ion solid-phase extraction for animal lipids with a low trans content[J]. European Journal of Lipid Science & Technology, 2015, 116 (12): 1621- 1625. |
[1] | 建晓朋,许伟,侯兴隆,刘石彩. 活性炭改性技术研究进展[J]. 生物质化学工程, 2020, 54(5): 66-72. |
[2] | 刘学,李淑君,刘守新,李坚,陈志俊. 木质素纳米颗粒的制备及其功能化应用研究进展[J]. 生物质化学工程, 2020, 54(5): 53-65. |
[3] | 曾维星,程贤,张笮晦,毕良武,赵振东. 生物预处理技术在天然产物提取中的应用研究进展[J]. 生物质化学工程, 2020, 54(5): 45-52. |
[4] | 曲晓萌,杨革,张泽浩,张兰. 纳滤法制备高纯度雪莲果低聚果糖及其结构表征[J]. 生物质化学工程, 2020, 54(5): 37-44. |
[5] | 宋国强,李欢,曹引梅,唐龙. MES表面活性剂的工业化精制工艺[J]. 生物质化学工程, 2020, 54(5): 33-36. |
[6] | 王盟盟,刘乐群,刘震涛,赵莹. 竹材液化墙体泡沫材料的阻燃改性[J]. 生物质化学工程, 2020, 54(5): 25-32. |
[7] | 吕鹏,王光辉,王冰,胡德玉. 热解温度和生物质类型对生物炭吸附U(Ⅵ)性能的影响[J]. 生物质化学工程, 2020, 54(5): 15-24. |
[8] | 岳春坡,余志凌,于千惠,王涛,王鹏搏,邸明伟. 射流等离子体放电气氛对木塑复合材料表面性质的影响[J]. 生物质化学工程, 2020, 54(5): 8-14. |
[9] | 翟兆兰,吕仆,赵平,宋湛谦,商士斌,饶小平. 脱氢枞基含氮衍生物的抑菌活性研究[J]. 生物质化学工程, 2020, 54(5): 1-7. |
[10] | 代琪琪,魏小翠,汤宏彪,李进,王晋京. 椰衣微波热解工艺的响应面法优化及液体产物组成分析[J]. 生物质化学工程, 2020, 54(4): 42-48. |
[11] | 孙琳,刘华玉,刘坤,张筱仪,解洪祥,张蕊,李海明,司传领. 纳米纤维素的疏水改性及应用研究进展[J]. 生物质化学工程, 2020, 54(4): 57-66. |
[12] | 尚玮姣,王璐. 基于专利的纳米纤维素技术现状与分析[J]. 生物质化学工程, 2020, 54(4): 49-56. |
[13] | 徐茹婷,许伟,卢辛成,孙康. 磷酸法木质活性炭除灰新工艺研究[J]. 生物质化学工程, 2020, 54(4): 37-41. |
[14] | 刘永旭,张大伟. 壳聚糖/聚乙烯醇/壳寡糖抑菌纳米纤维膜的制备和性能研究[J]. 生物质化学工程, 2020, 54(4): 30-36. |
[15] | 刘菲菲,王岚,李佐虎,陈洪章. 汽爆秸秆对磷矿粉溶解作用及其溶解残渣对小麦生长的影响[J]. 生物质化学工程, 2020, 54(4): 23-29. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||