5-羟甲基糠醛与乙酰丙酸制备生物基化学品的研究进展

doi:10.3969/j.issn.1673-5854.2016.04.010

生物质化学工程 ›› 2016, Vol. 50 ›› Issue (4): 53-59.doi: 10.3969/j.issn.1673-5854.2016.04.010

5-羟甲基糠醛与乙酰丙酸制备生物基化学品的研究进展

朱仕林¹, 李静丹¹, 姜小祥^1,2, 杨宏旻¹, 蒋剑春², 张爱玲¹

1. 江苏省能源系统过程转化与减排技术工程实验室; 南京师范大学能源与机械工程学院, 江苏南京 210042;
2. 中国林业科学研究院林产化学工业研究所;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2016-02-28 出版日期:2016-07-31 发布日期:2016-10-08
通讯作者: 姜小祥,副教授,博士,博士后,研究领域为生物质能源资源化利用;E-mail:62081@njnu.edu.cn。 E-mail:62081@njnu.edu.cn
作者简介:朱仕林(1995-),女,山西朔州人,本科生,从事生物质能源资源化利用;E-mail:jiangxx0110@sina.cn
基金资助:
江苏省自然科学基金（BK20141451）；江苏省高校自然科学基金（14KJB480003）

Process of Conversion of 5-Hydroxymethylfurfural and Levulinic Acid to Biomass-based Chemicals

ZHU Shi-lin¹, LI Jing-dan¹, JIANG Xiao-xiang^1,2, YANG Hong-min¹, JIANG Jian-chun², ZHANG Ai-ling¹

1. Engineering Laboratory for Energy System Process Conversion & Emission Control Technology of Jiangsu Province;School of Energy & Mechanical Engineering, Nanjing Normal University, Nanjing 210042, China;
2. Institute of Chemical Industry of Forest Product, CAF;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2016-02-28 Online:2016-07-31 Published:2016-10-08

摘要/Abstract

摘要： 综述了生物质基平台分子5-羟甲基糠醛及乙酰丙酸转化制备多种化学品的研究进展，主要包括5-羟甲基糠醛转化为2，5-呋喃二甲酸、2，5-呋喃二甲醛、2，5-二甲基呋喃的过程以及乙酰丙酸转化为酯类、酸类、吡咯烷酮及双酚酸。简要介绍了这几种生物基化学品的用途、生产工艺以及其中存在的问题，旨在为发展从生物质平台分子制备生物基化学品的工业生产提供指导意义。

关键词: 5-羟甲基糠醛, 乙酰丙酸, 化学品

Abstract: The processes of the conversion of biomass-based platforms molecules 5-hydroxymethylfurfural(HMF) and levulinic acid(LA) to chemicals were reviewed.This paper mainly included HMF to 2, 5-furandicarboxylic acid, 2, 5-diformylfuran and 2, 5-dimethylfuran and LA to esters, acids, pyrrolidione and diphenolic acid.The use, producing process and the existing problems were briefly introduced.The object of this paper aimed to provide the guiding significance for developing the industrial production process of bio based chemicals from biomass platform molecules.

Key words: 5-hydroxymethylfurfural, levulinic acid, chemicals

中图分类号:

TQ35

朱仕林, 李静丹, 姜小祥, 杨宏旻, 蒋剑春, 张爱玲. 5-羟甲基糠醛与乙酰丙酸制备生物基化学品的研究进展[J]. 生物质化学工程, 2016, 50(4): 53-59.

ZHU Shi-lin, LI Jing-dan, JIANG Xiao-xiang, YANG Hong-min, JIANG Jian-chun, ZHANG Ai-ling. Process of Conversion of 5-Hydroxymethylfurfural and Levulinic Acid to Biomass-based Chemicals[J]. bce, 2016, 50(4): 53-59.

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5-羟甲基糠醛与乙酰丙酸制备生物基化学品的研究进展

Process of Conversion of 5-Hydroxymethylfurfural and Levulinic Acid to Biomass-based Chemicals

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